Selective oxidation of carbohydrates by 4-AcNH-TEMPO/peracid systems

Carbohydrate Polymers

Volumn 49, Issue 4, 2002, Pages 397-406

  Bragd, Petter L ^a   Besemer, Arie C ^a   Van Bekkum, Herman ^b  

^a SCA Hygiene Products   (Netherlands)

^b DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

4 Acetamido 2,2,6,6 tetramethylpiperidine 1 oxyl; Amylopectin; Inulin; Methyl d glucopyranoside; Oxone; Peracetic acid; Pullulan; Starch

Indexed keywords

CATALYSIS; CATALYSTS; DEPOLYMERIZATION; MOLECULAR WEIGHT DISTRIBUTION; ORGANIC ACIDS; OXIDATION; RATE CONSTANTS; SODIUM COMPOUNDS;

SELECTIVE OXIDATIONS;

POLYSACCHARIDES;

EID: 0036721758     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0144-8617(01)00344-7     Document Type: Article

References (50)

1. Fast and selective oxidation of primary alcohols to aldehydes or to carboxylic acids and of secondary alcohols to ketones mediated by oxoammonium salts under two-phase conditions
2. The kinetics of the decomposition of Caro's acid
3. New method for quantitative determination of uronic acid
4. Organic nitrosonium salts as oxidants in organic chemistry
5. Catalytic synthesis of aldehydes and ketones under mild conditions using TEMPO/oxone
6. Bromide-free-TEMPO oxidation of starch and methyl α d-glucopyranoside
7. TEMPO-derivatives as catalysts in the oxidation of primary alcohol groups in carbohydrates
8. Nitroxide-catalysed oxidation of alcohols using m-chloroperbenzoic acid. A new method
9. Oxidation of primary alcohol groups of naturally occurring polysaccharides with 2,2,6,6-tetramethyl-1-piperidine oxoammonium ion
10. Oxidation of the primary alcohol groups of cyclomaltodextrins with 2,2,6,6-tetramethyl-1-piperidine oxoammonium ion
11. A versatile and highly selective hypervalent iodine (III)/2,2,6,6-tetramethyl-1-piperidinyloxyl-mediated oxidation of alcohols to carbonyl compounds
12. Highly selective radical-mediated oxidation of primary alcohol groups in water-soluble glucans
13. Selective oxidation of primary alcohols mediated ny nitroxyl radical in aqueous solution. Kinetics and mechanism
14. On the use of stable organic nitroxyl radicals for the oxidation of primary and secondary alcohols
15. Synthesis and preliminary characterisation of charged derivatives and hydrogels from scleroglucans
16. Efficient and highly selective oxidation of primary alcohols to aldehydes by N-chlorosuccinimide mediated by oxoammonium salts
17. Oxidation of hydroxide ion by immonium oxide
18. Analysis of aliphatic peracids
19. Factors governing the ratio of isomeric oxabicyclo[3.2.1]octanones formed on Bayer-Villiger oxidation of some 5-endo, 7-anti-disubstituted bicyclo[2.2.1]heptan-2-ones
20. Synthesis of α- and β-d-glucopyranuronate 1-phosphate and α-d-glucopyranuronate 1-fluoride: Intermediates and the synthesis of glucuronic acid from starch
21. The selective catalytic oxidation of terminal alcohols: A novel four-component system with MTO as catalyst
22. Oxidation of s-alcohols with oxone in aprotic solvents in the presence of wet-aluminium oxide
23. Oxoammonium salts as oxidising agents: 2,2,6,6-tetramethyl-1-oxopiperidinium chloride
24. Preparation of polyuronic acid from cellulose by TEMPO-mediated oxidation
25. A selective method for alcohol oxidations mediated by N-oxoammonium salts in combination with sodium bromite
26. Study on TEMPO-mediated selective oxidation of hyaluronan and the effects of salt on the reaction kinetics
27. The oxidation of organic substances by potassium peroxymonosulfate
28. Regioselective oxidation of hydroxyl groups of sugar and its derivatives using silver catalysts mediated by TEMPO and peroxodisulfate in water
29. Sucrose tricarboxylate by sonocatalysed TEMPO-mediated oxidation
30. Oxidation of primary alcohols to carboxylic acids with sodium chlorite catalysed by TEMPO and bleach
31. Oxidation of benzyl alcohol by Fe(III) mediated by nitroxyl radical
32. Oxidation of aliphatic secondary and benzylic alcohols to carbonyl compounds by peracetic acid in the presence of sodium bromide in acetic acid
33. Polyuronans obtained by regiospecific oxidation of polysaccharides from Aspergillus niger Trichoderma reesei and Saprolegnia sp
34. 6-oxychitins, novel hyaluronans-like regiospecifically carboxylated chitins
35. Mechanism of the Fe(III)-catalysed peracetic acid oxidation of catechol. A biomimetic reaction for pyrocatechase
36. Low temperature bleaching of cotton with peracetic acid
37. 2,2′-bipyridine catalyzed bleaching of cotton fibers with peracetic acid. Part I: Kinetics and mechansim of peracetic acid decomposition in the bleach solution
38. Electroorganic synthesis 66: Selective anodic oxidation of carbohydrates mediated by TEMPO
39. Oxidation of alcohols to aldehydes with oxygen and cupric ion, mediated by nitrosonium ion
40. Mechanism of the reaction of hydrogen peroxide with oxopiperidine salts and piperidinoxyl radicals
41. Consider the environmental quotient
42. Specific modfications of galactomannans
43. Caro's acid brightening of chemical pulp
44. The preparation of peracids for bleaching
45. Alkaline degradation of polysaccharides
46. Fractionation of starch