The participation of alkynylboronates in inverse electron demand [4 + 2] cycloadditions: A mechanistic study

Journal of the American Chemical Society

Volumn 129, Issue 9, 2007, Pages 2691-2699

  Gomez Bengoa, Enrique ^a   Helm, Matthew D ^b   Plant, Andrew ^c   Harrity, Joseph P A ^b  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

^c JEALOTT S HILL INTERNATIONAL RESEARCH CENTRE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON BEAMS; OLEFINS; PHASE TRANSITIONS; PROBABILITY DENSITY FUNCTION; REACTION KINETICS;

CYCLOADDITION MECHANISM; ELECTRON-RICH DIENES; SYNCHRONOUS TRANSITION;

NITROGEN COMPOUNDS;

ACETYLENE; ACETYLENEDICARBOXYLIC ACID DIMETHYL ESTER; ALKYNYL GROUP; BORONIC ACID DERIVATIVE; CHLORINE DERIVATIVE; FURAN DERIVATIVE; TETRAZINE DERIVATIVE; TRIMETHYLSILYL DERIVATIVE;

ARTICLE; CALCULATION; CHEMICAL REACTION; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; PHASE TRANSITION; REACTION ANALYSIS;

EID: 33847611084     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja068527k     Document Type: Article

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