Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups

Bulletin of the Chemical Society of Japan

Volumn 80, Issue 2, 2007, Pages 371-386

  Hayashi, Naoto ^a   Nishihara, Takashi ^a   Matsukihira, Takuya ^a   Nakashima, Hiroki ^a   Miyabayashi, Keiko ^b   Miyake, Mikio ^b   Higuchi, Hiroyuki ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

^b JAPAN ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; DERIVATIVES; ISOMERS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

DIACETYLENE LINKAGE; ELECTRON-WITHDRAWING GROUPS; ELECTRON-WITHDRAWING SUBSTITUENTS; ORIENTATIONAL ISOMERS;

OLEFINS;

ACETYLENE DERIVATIVE; PORPHYRIN DERIVATIVE; THIOPHENE DERIVATIVE;

ABSORPTION SPECTROPHOTOMETRY; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ISOMER; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 33847106458     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.80.371     Document Type: Article

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60. The synthetic strategy shown in the present work is not suitable for the synthesis of the derivatives 26 with TH orientation of DHBTh. Thus, the study to find new synthetic strategy for 26 is now underway. The synthetic success of 26 should enable us discuss conclusively about the substituent effect on not only oxidation potentials but also reduction potentials of the OEP derivatives. The substituent effect on the electronic properties of all the OEP derivatives including 26 will be reported continuously, as compared with the orientation effect of DHBTh.