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Volumn , Issue 8, 2007, Pages 866-870

Bis- and tris(2-seleno-1-methylimidazolyl)hydroborato complexes, {Bse MeZnX}2 (X = Cl, I), BseMe2Zn and TseMeRe(CO)3: Structural evidence that the Bse Me ligand is not merely a "heavier" version of the sulfur counterpart, BmMe

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; ELECTRON BEAMS; MOLECULAR STRUCTURE; REACTION KINETICS; STRUCTURAL ANALYSIS;

EID: 33847076422     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b616630j     Document Type: Article
Times cited : (27)

References (46)
  • 31
    • 84942817238 scopus 로고    scopus 로고
    • note
    • MeNa has not been determined by X-ray diffraction and the connectivity shown in Scheme 1 is only intended to be illustrative.
  • 32
    • 84942830497 scopus 로고    scopus 로고
    • note
    • 2 suggest that the dinuclear structure is maintained in solution.
  • 36
    • 21344452465 scopus 로고
    • For comparison, the sum of covalent radii of Zn and Se is 2.42 Å. See: S. S. Batsanov Russ. Chem. Bull. 1995 44 2245 2250
    • (1995) Russ. Chem. Bull. , vol.44 , pp. 2245-2250
    • Batsanov, S.S.1
  • 37
    • 0344436712 scopus 로고    scopus 로고
    • It is important to note that the longer Zn-Se bond lengths are considerably smaller than the sum of the crystallographic van der Waals radii of Zn and Se (4.0 Å). See: S. S. Batsanov Inorg. Mater. 2001 37 871 885
    • (2001) Inorg. Mater. , vol.37 , pp. 871-885
    • Batsanov, S.S.1
  • 38
    • 84942832208 scopus 로고    scopus 로고
    • note
    • For other examples of complexes that exhibit 3-center-2-electron B-H⋯Zn interactions, see ref. 6 and 7k.
  • 39
    • 84942838540 scopus 로고    scopus 로고
    • note
    • MesZnI is 2.48 Å. See ref. 8.
  • 40
    • 84942833282 scopus 로고    scopus 로고
    • note
    • 2Zn (177°).
  • 41
    • 84942822991 scopus 로고    scopus 로고
    • note
    • 2Zn also adopts a "chair-like" configuration. See ref. 6a.
  • 43
    • 0003806926 scopus 로고
    • A. L. Wayda and M. Y. Darensbourg, American Chemical Society, Washington, DC, pp. 79-98
    • B. J. Burger and J. E. Bercaw, in Experimental Organometallic Chemistry, ed., A. L. Wayda, and, M. Y. Darensbourg, American Chemical Society, Washington, DC, 1987, ch. 4, pp. 79-98
    • (1987) Experimental Organometallic Chemistry, Ed.
    • Burger, B.J.1    Bercaw In, J.E.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.