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Volumn , Issue 6, 2000, Pages 891-897

The synthesis and structural characterization of bis(mercaptoimidazolyl)hydroborato complexes of lithium, thallium and zinc

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EID: 0001960882     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/a908411h     Document Type: Article
Times cited : (104)

References (38)
  • 4
    • 84943967614 scopus 로고    scopus 로고
    • Bis- and tris-(2-mercapto-l-alkylimidazolyl)borate ligands are represented by the abbreviations [BmR] and [TmR], respectively.
    • Respectively.
  • 8
    • 0010636960 scopus 로고    scopus 로고
    • 1993, 93, 943; G. Parkin, Adv. Inorg. Chem., 1995, 42, 291; N. Kitajima and W. B. Tolman, Prog. Inorg. Chem., 1995,43,419.
    • For reviews, see: S. Trofimenko, Chem. Rev., 1993, 93, 943; G. Parkin, Adv. Inorg. Chem., 1995, 42, 291; N. Kitajima and W. B. Tolman, Prog. Inorg. Chem., 1995,43,419.
    • See: S. Trofimenko, Chem. Rev.
    • Reviews, F.1
  • 10
    • 0043074963 scopus 로고    scopus 로고
    • 1998, 21, 33; Coord. Chem. Rev., 1997,163, 107.
    • C. Janiak, Main Group Met. Chem., 1998, 21, 33; Coord. Chem. Rev., 1997,163, 107.
    • Main Group Met. Chem.
    • Janiak, C.1
  • 11
    • 33746540685 scopus 로고    scopus 로고
    • 2Jc (No. 14), 0 = 7.5661(5), 6 = 20.740(1), c = 7.3572(5) A, = 90.000(1)°, K= 1154.5(1) A3, Z = 4, 7=223 K, #, = 0.0394, H'/?3 = 0.1119[/>2<7(/)].
    • 2-Mercapto-l-mesitylimidazole is monoclinic, space group P2Jc (No. 14), 0 = 7.5661(5), 6 = 20.740(1), c = 7.3572(5) A, = 90.000(1)°, K= 1154.5(1) A3, Z = 4, 7=223 K, #, = 0.0394, H'/?3 = 0.1119[/>2<7(/)].
    • Space Group P
    • Monoclinic, M.-L.1
  • 12
    • 33746477672 scopus 로고    scopus 로고
    • An orthorhombic modification of [BmMt]ZnI was also structurally characterized: a = 9.075(1), 6=10.800(1), c = 29.261(5) A, K= 2868.0(8) A3, Z = 8, T=293 K, #, = 0.0490, iv#2 = 0.1215 [7>2
    • An orthorhombic modification of [BmMt]ZnI was also structurally characterized: a = 9.075(1), 6=10.800(1), c = 29.261(5) A, K= 2868.0(8) A3, Z = 8, T=293 K, #, = 0.0490, iv#2 = 0.1215 [7>2
  • 13
    • 33746498001 scopus 로고    scopus 로고
    • CSD Version 5.17. 3D Search and Research Using the Cambridge Structural Database,f. H.AlIenandO.Kennard, Chem. Des. Automat. MM, 1993, 8(1), 1,31.
    • CSD Version 5.17. 3D Search and Research Using the Cambridge Structural Database,f. H.AlIenandO.Kennard, Chem. Des. Automat. MM, 1993, 8(1), 1,31.
  • 14
    • 33746484688 scopus 로고    scopus 로고
    • 1 centers in a variety of [BpRR']Tl complexes are supplemented by weak intramolecular [Tl H-B] interactions. T. Fillebeen, T. Hascall and G. Parkin, Inorg. Chem., 1997,36, 3787; P. Ghosh, T. Hascall, C.-Dowling and G. Parkin, / Chem. Soc., Dation Trans., 1998, 3355; C. Dowling, P. Ghosh and G. Parkin, Polyhedron, 1997, 16, 3469.
    • For example, the "two coordinate" Tl1 centers in a variety of [BpRR']Tl complexes are supplemented by weak intramolecular [Tl H-B] interactions. T. Fillebeen, T. Hascall and G. Parkin, Inorg. Chem., 1997,36, 3787; P. Ghosh, T. Hascall, C.-Dowling and G. Parkin, / Chem. Soc., Dation Trans., 1998, 3355; C. Dowling, P. Ghosh and G. Parkin, Polyhedron, 1997, 16, 3469.
    • The "Two Coordinate" Tl
    • Example, F.1
  • 26
    • 0001485424 scopus 로고    scopus 로고
    • 1999,38, 1900; U. Brand, M. Rombach and H. Vahrenkamp, Client. Commun., 1998, 2717; U. Brand and H. Vahrenkamp, Z. Anorg. Allg. Client., 1996,622,213.
    • For recent references to tetrahedral zinc complexes with sulfur ligation, see: B. Muller, A. Schneider, M. Tesmer and H. Vahrenkamp, Inorg. Client., 1999,38, 1900; U. Brand, M. Rombach and H. Vahrenkamp, Client. Commun., 1998, 2717; U. Brand and H. Vahrenkamp, Z. Anorg. Allg. Client., 1996,622,213.
    • See: B. Muller, A. Schneider, M. Tesmer and H. Vahrenkamp, Inorg. Client.
    • Ligation, F.R.R.1
  • 37
    • 33746525653 scopus 로고    scopus 로고
    • Note that {[Bm"':s]Tl}.t decomposes over the period of an hour in Me2SO.
    • Note that {[Bm"':s]Tl}.t decomposes over the period of an hour in Me2SO.


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