Phenyltris((tert-butylthio)methyl)borate: A Second Generation S3- Ligand That Enforces Tetrahedral Coordination

Inorganic Chemistry

Volumn 37, Issue 19, 1998, Pages 4754-4755

  Schebler, Peter J ^a   Riordan, Charles G ^a   Guzei, Ilia A ^a   Rheingold, Arnold L ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000713320     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980514n     Document Type: Article

References (26)

1. (a) Ge, P.; Riordan, C. G.; Haggerty, B. S.; Rheingold, A. L. J. Am. Chem. Soc. 1994, 116, 8406-8407.
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3. (c) Ohrenberg, C.; Saleem, M. M.; Riordan, C. G.; Yap, G. P. A.; Rheingold, A. L. J. Chem. Soc., Chem. Commun. 1996, 1081-1082.
4. (d) Ge, P.; Riordan, C. G.; Yap, G. P. A.; Rheingold, A. L. Inorg. Chem. 1996, 35, 5408-5409.
5. (e) Schebier, P.; Riordan, C. G.; Liable-Sands, L.; Rheingold, A. L. Inorg. Chim. Acta 1998, 270, 543-549.
6. -, diphenyibis((methylthio)methyl)borate.
7. Ohrenberg, C.; Riordan, C. G.; Liable-Sands, L.; Rheingofd, A. L. Coord. Chem. Rev. 1998, in press.
8. Complete data contained in Supporting Information.
9. 3Tl: C, 41.9; H, 6.36. Found: C, 41.7; H, 6.32.
10. 3, R(F) = 4.12% for 3698 observed independent reflections (4 ≤ 2θ ≤ 56°). Empirical absorption corrections were applied for 1 using the program DIFABS. All non-hydrogen atoms (except one disordered atom, C(8) in 1) were refined anisotropically. Hydrogen atoms were treated as idealized contributions. 2 and 3 are isomorphous. DIFABS is described by N. Walker and D. Stuart in Acta Crystallogr. 1983, A39, 158-166,
11. 3: C, 51.3; H, 7.79. Found: C, 49.7; H, 7.71.
12. For representative examples of Co(II) thioether complexes, see: (a) Kajitani, M.; Hatano, H.; Fujita, T.; Okumachi, T.; Nagao, H.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1992, 430, C64-C67. (b) Sheldriek, W. S.; Hauck, E.; Korn, S. J. Organmet. Chem. 1994, 467, 283-292. (c) Takayama, C.; Sakamoto, N.; Harada, T.; Kajitani, M.; Sugiyama, T.; Akiyama, T.; Sugimori, A. Organetmetallic 1996, 15, 5077-5079. A search of the Cambridge Crystallograpnic Database found no tetrahedral Ni(II) thioether complexes, For representative examples of Ni(II) thioether derivatives in square planar geometries, see: (a) Davis, P. H.; White, L. K.; Beiford, R. L. Inorg. Chem. 1975, 14, 1753-1757. (b) Mills, D. K.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1990, 29, 4364-4366. (c) Yamamura, T.; Aral, H.; Nakamura, N.; Miyumae H. Chem. Lett. 1990, 2121-2124. (d) Desper, J. M.; Vyvyan, J. R.; Mayer, M. J.; Ochrymowycz, L. A.; Gellman, S. H. Inorg. Chem. 1993, 32, 381-382.
13. For representative examples of Co(II) thioether complexes, see: (a) Kajitani, M.; Hatano, H.; Fujita, T.; Okumachi, T.; Nagao, H.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1992, 430, C64-C67. (b) Sheldriek, W. S.; Hauck, E.; Korn, S. J. Organmet. Chem. 1994, 467, 283-292. (c) Takayama, C.; Sakamoto, N.; Harada, T.; Kajitani, M.; Sugiyama, T.; Akiyama, T.; Sugimori, A. Organetmetallic 1996, 15, 5077-5079. A search of the Cambridge Crystallograpnic Database found no tetrahedral Ni(II) thioether complexes, For representative examples of Ni(II) thioether derivatives in square planar geometries, see: (a) Davis, P. H.; White, L. K.; Beiford, R. L. Inorg. Chem. 1975, 14, 1753-1757. (b) Mills, D. K.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1990, 29, 4364-4366. (c) Yamamura, T.; Aral, H.; Nakamura, N.; Miyumae H. Chem. Lett. 1990, 2121-2124. (d) Desper, J. M.; Vyvyan, J. R.; Mayer, M. J.; Ochrymowycz, L. A.; Gellman, S. H. Inorg. Chem. 1993, 32, 381-382.
14. For representative examples of Co(II) thioether complexes, see: (a) Kajitani, M.; Hatano, H.; Fujita, T.; Okumachi, T.; Nagao, H.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1992, 430, C64-C67. (b) Sheldriek, W. S.; Hauck, E.; Korn, S. J. Organmet. Chem. 1994, 467, 283-292. (c) Takayama, C.; Sakamoto, N.; Harada, T.; Kajitani, M.; Sugiyama, T.; Akiyama, T.; Sugimori, A. Organetmetallic 1996, 15, 5077-5079. A search of the Cambridge Crystallograpnic Database found no tetrahedral Ni(II) thioether complexes, For representative examples of Ni(II) thioether derivatives in square planar geometries, see: (a) Davis, P. H.; White, L. K.; Beiford, R. L. Inorg. Chem. 1975, 14, 1753-1757. (b) Mills, D. K.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1990, 29, 4364-4366. (c) Yamamura, T.; Aral, H.; Nakamura, N.; Miyumae H. Chem. Lett. 1990, 2121-2124. (d) Desper, J. M.; Vyvyan, J. R.; Mayer, M. J.; Ochrymowycz, L. A.; Gellman, S. H. Inorg. Chem. 1993, 32, 381-382.
15. For representative examples of Co(II) thioether complexes, see: (a) Kajitani, M.; Hatano, H.; Fujita, T.; Okumachi, T.; Nagao, H.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1992, 430, C64-C67. (b) Sheldriek, W. S.; Hauck, E.; Korn, S. J. Organmet. Chem. 1994, 467, 283-292. (c) Takayama, C.; Sakamoto, N.; Harada, T.; Kajitani, M.; Sugiyama, T.; Akiyama, T.; Sugimori, A. Organetmetallic 1996, 15, 5077-5079. A search of the Cambridge Crystallograpnic Database found no tetrahedral Ni(II) thioether complexes, For representative examples of Ni(II) thioether derivatives in square planar geometries, see: (a) Davis, P. H.; White, L. K.; Beiford, R. L. Inorg. Chem. 1975, 14, 1753-1757. (b) Mills, D. K.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1990, 29, 4364-4366. (c) Yamamura, T.; Aral, H.; Nakamura, N.; Miyumae H. Chem. Lett. 1990, 2121-2124. (d) Desper, J. M.; Vyvyan, J. R.; Mayer, M. J.; Ochrymowycz, L. A.; Gellman, S. H. Inorg. Chem. 1993, 32, 381-382.
16. For representative examples of Co(II) thioether complexes, see: (a) Kajitani, M.; Hatano, H.; Fujita, T.; Okumachi, T.; Nagao, H.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1992, 430, C64-C67. (b) Sheldriek, W. S.; Hauck, E.; Korn, S. J. Organmet. Chem. 1994, 467, 283-292. (c) Takayama, C.; Sakamoto, N.; Harada, T.; Kajitani, M.; Sugiyama, T.; Akiyama, T.; Sugimori, A. Organetmetallic 1996, 15, 5077-5079. A search of the Cambridge Crystallograpnic Database found no tetrahedral Ni(II) thioether complexes, For representative examples of Ni(II) thioether derivatives in square planar geometries, see: (a) Davis, P. H.; White, L. K.; Beiford, R. L. Inorg. Chem. 1975, 14, 1753-1757. (b) Mills, D. K.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1990, 29, 4364-4366. (c) Yamamura, T.; Aral, H.; Nakamura, N.; Miyumae H. Chem. Lett. 1990, 2121-2124. (d) Desper, J. M.; Vyvyan, J. R.; Mayer, M. J.; Ochrymowycz, L. A.; Gellman, S. H. Inorg. Chem. 1993, 32, 381-382.
17. For representative examples of Co(II) thioether complexes, see: (a) Kajitani, M.; Hatano, H.; Fujita, T.; Okumachi, T.; Nagao, H.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1992, 430, C64-C67. (b) Sheldriek, W. S.; Hauck, E.; Korn, S. J. Organmet. Chem. 1994, 467, 283-292. (c) Takayama, C.; Sakamoto, N.; Harada, T.; Kajitani, M.; Sugiyama, T.; Akiyama, T.; Sugimori, A. Organetmetallic 1996, 15, 5077-5079. A search of the Cambridge Crystallograpnic Database found no tetrahedral Ni(II) thioether complexes, For representative examples of Ni(II) thioether derivatives in square planar geometries, see: (a) Davis, P. H.; White, L. K.; Beiford, R. L. Inorg. Chem. 1975, 14, 1753-1757. (b) Mills, D. K.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1990, 29, 4364-4366. (c) Yamamura, T.; Aral, H.; Nakamura, N.; Miyumae H. Chem. Lett. 1990, 2121-2124. (d) Desper, J. M.; Vyvyan, J. R.; Mayer, M. J.; Ochrymowycz, L. A.; Gellman, S. H. Inorg. Chem. 1993, 32, 381-382.
18. For representative examples of Co(II) thioether complexes, see: (a) Kajitani, M.; Hatano, H.; Fujita, T.; Okumachi, T.; Nagao, H.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1992, 430, C64-C67. (b) Sheldriek, W. S.; Hauck, E.; Korn, S. J. Organmet. Chem. 1994, 467, 283-292. (c) Takayama, C.; Sakamoto, N.; Harada, T.; Kajitani, M.; Sugiyama, T.; Akiyama, T.; Sugimori, A. Organetmetallic 1996, 15, 5077-5079. A search of the Cambridge Crystallograpnic Database found no tetrahedral Ni(II) thioether complexes, For representative examples of Ni(II) thioether derivatives in square planar geometries, see: (a) Davis, P. H.; White, L. K.; Beiford, R. L. Inorg. Chem. 1975, 14, 1753-1757. (b) Mills, D. K.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1990, 29, 4364-4366. (c) Yamamura, T.; Aral, H.; Nakamura, N.; Miyumae H. Chem. Lett. 1990, 2121-2124. (d) Desper, J. M.; Vyvyan, J. R.; Mayer, M. J.; Ochrymowycz, L. A.; Gellman, S. H. Inorg. Chem. 1993, 32, 381-382.
19. (e) Sellmann, D.; Haussinger, D.; Knoch, F.; Moll, M. J. Am. Chem. Soc. 1996, 118, 5368-5374.
20. (a) Trofimenko, S. Chem. Rev. 1993, 93, 943-980.
21. (b) Liable-Sands, L.; Rheingold, A. L. Unpublished result.
22. Ge, P.; Riordon, C. G.; Rheingold, A. L. Unpublished result.
23. -1): 222 (9900), 267 (3200), 274 (3200), 307 (2400), 470 (210), EPR (X-band, THF, 77 K) g values: 2.40, 2.18, 2.12.
24. (a) Macgregor, S. A.; Lu, Z.; Eisenstein, O.; Crabtree, R. H. Inorg. Chem. 1994, 33, 3616-3618.
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