Electrophilic O-methylation of a terminal nitrosyl ligand attained by an early-late heterobimetallic effect

Organometallics

Volumn 25, Issue 3, 2006, Pages 560-562

  Arashiba, Kazuya ^a   Matsukawa, Shoji ^b   Kuwata, Shigeki ^c   Tanabe, Yoshiaki ^a   Iwasaki, Masakazu ^d   Ishii, Youichi ^a,e  

^a CHUO UNIVERSITY   (Japan)

^b INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

^c TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^d SAITAMA INSTITUTE OF TECHNOLOGY   (Japan)

^e INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; MOLECULAR STRUCTURE; REACTION KINETICS;

ELECTROPHILIC O-METHYLATION; METHOXYIMIDO COMPLEX;

ORGANOMETALLICS;

EID: 33644509811     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0510573     Document Type: Article

References (34)

1. (a) Wheatley, N.; Kalck, P. Chem. Rev. 1999, 99, 3379.
2. (b) Stephan, D. W. Coord. Chem. Rev. 1989, 95, 41.
3. (a) Hanna, T. A.; Baranger, A. M.; Bergman, R. G. J. Am. Chem. Soc. 1995, 117, 11363.
4. (b) Hidai, M.; Kuwata, S.; Mizobe, Y. Acc. Chem. Res. 2000, 33, 46.
5. (c) Cornelissen, C.; Erker, G.; Kehr, G.; Fröhlich, R. Organometallics 2005, 24, 214.
6. (a) Hayton, T. W.; Legzdins, P.; Sharp, W. B. Chem. Rev. 2002, 102, 935.
7. (b) Ford, P. C.; Lorkovic, I. M. Chem. Rev. 2002, 102, 993.
8. (a) Hattori, T.; Matsukawa, S.; Kuwata, S.; Ishii, Y.; Hidai, M. Chem. Commun. 2003, 510.
9. (b) Matsukawa, S.; Kuwata, S.; Hidai, M. Inorg. Chem. 2000, 39, 791.
10. (a) Kuwata, S.; Hidai, M. Coord. Chem. Rev. 2001, 213, 211.
11. (b) Peruzzini, M.; de los Rios, I.; Romerosa, A. Prog. Inorg. Chem. 2001, 49, 169.
12. (c) Kuwata, S.; Nagano, T.; Matsubayashi, A.; Ishii, Y.; Hidai, M. Inorg. Chem. 2002, 41, 4324.
13. See the Supporting Information.
14. (a) Hayton, T. W.; Legzdins, P.; Patric, B. O. Inorg. Chem. 2002, 41, 5388.
15. (b) Müller, A.; Eltzner, W.; Clegg, W.; Sheldrick, G. M. Angew. Chem., Int. Ed. 1982, 21, 536.
16. (c) Chen, Z.; Schmalle, H. W.; Fox, T.; Berke, H. Dalton Trans. 2005, 580.
17. Jin, G.-X.; Herberhold, M. Transition Met. Chem. 2001, 26, 445.
18. W) = 0.037 (0.038) for 620 variables and 8566 reflections (I > 3σ(I)), GOF = 1.012.
19. Herberhold, M.; Jin, G.-X.; Kremnitz, W.; Rheingold, A. L.; Haggerty, B. S. Z. Naturforsch. 1991, 46b, 500.
20. Gomez-Sal, P.; de Jesús, E.; Michiels, W.; Royo, P.; de Miguel, A. V.; Martínez-Carrera, S. J. Chem. Soc., Dalton Trans. 1990, 2445.
21. 3)] are known to reduce the hapticity of the Cp ligands to a greater extent: (a) Cotton, F. A.; Rusholme, G. A. J. Am. Chem. Soc. 1972, 94, 402.
22. (b) Shin, J. H.; Bridgewater, B. M.; Churchill, D. G.; Baik, M.-H.; Friesner, R. A.; Parkin, G. J. Am. Chem. Soc. 2001, 123, 10111.
23. Herring, F. G.; Legzdins, P.; Richter-Addo, G. B. Organometallics 1989, 8, 1485.
24. w) = 0.030 (0.031) for 422 variables and 6041 reflections (I > 3σ(I)), GOF = 1.018.
25. Green, M. L. H.; James, J. T.; Sanders, J. F. J. Chem. Soc., Chem. Commun. 1996, 1343.
26. Sharp, W. B.; Daff, P. J.; McNeil, W. S.; Legzdins, P. J. Am. Chem. Soc. 2001, 123, 6272.
27. (a) Stevens, R. E.; Gladfelter, W. L. J. Am. Chem. Soc. 1982, 104, 6454.
28. (b) Stevens, R. E.; Guettler, R. D.; Gladfelter, W. L. Inorg. Chem. 1990, 29, 451.
29. (c) Barr, M. E.; Bjarnason, A.; Dahl, L. F. Organometallics 1994, 13, 1981.
30. (d) Lee, K. K. H.; Wong, W. T. J. Chem. Soc., Dalton Trans. 1996, 1707.
31. (a) Farmer, P. J.; Sulc, F. J. Inorg. Biochem. 2005, 99, 166.
32. (b) Melenkivitz, R.; Hillhouse, G. L. Chem. Commun. 2002, 660.
33. Sharp, W. B.; Legzdins, P.; Patrick, B. O. J. Am. Chem. Soc. 2001, 123, 8143.
34. w) = 0.053 (0.054) for 1133 variables and 8584 reflections (I > 3σ(I)), GOF = 1.014.