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Volumn , Issue 7, 2007, Pages 722-724

Organocatalytic asymmetric hydrophosphination of nitroalkenes

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE;

EID: 33846940466     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b613477g     Document Type: Article
Times cited : (100)

References (32)
  • 22
    • 33947116027 scopus 로고
    • For recent studies on organocatalytic addition of pentavalent phosphorus compounds to unsaturated substrates, see:
    • W. A. Henderson, Jr. C. A. Streuli J. Am. Chem. Soc. 1960 82 5791
    • (1960) J. Am. Chem. Soc. , vol.82 , pp. 5791
    • Henderson Jr., W.A.1    Streuli, C.A.2
  • 25
    • 0346365499 scopus 로고    scopus 로고
    • Phosphine-borane deprotection can be easily accomplished under mild conditions, see:
    • J. McNulty Y. Zhou Tetrahedron Lett. 2004 45 407
    • (2004) Tetrahedron Lett. , vol.45 , pp. 407
    • McNulty, J.1    Zhou, Y.2
  • 31
    • 33644747543 scopus 로고    scopus 로고
    • Other nucleophilic phosphorus reagents examined included di-tert-butylphosphine (0% ee), 1-borane complex (0% ee) and diphenylphosphine oxide (20% ee, 30% conversion, 24 h)
    • A. L. Tillman J. Ye D. J. Dixon Chem. Commun. 2006 1191
    • (2006) Chem. Commun. , pp. 1191
    • Tillman, A.L.1    Ye, J.2    Dixon, D.J.3
  • 32
    • 33846939068 scopus 로고    scopus 로고
    • 3: 0% ee) The sense of stereochemical induction is in agreement with a previously reported selectivity model, in which the selective binding of the nitroolefin with the thiourea framework of the bifunctional catalyst D through a double-hydrogen bonding mechanism directs the nucleophilic attack at the Si-face of the electrophile. See ref. 17b
    • 3: 0% ee)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.