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Volumn 45, Issue 26, 2006, Pages 10428-10430

Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

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EID: 33846578349     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic061741p     Document Type: Article
Times cited : (26)

References (36)
  • 14
    • 33846592344 scopus 로고    scopus 로고
    • Crystal data: 3·CH2Cl2, purple prism, C93H56Cl2N8O4Rh 4, Mw 1832.00, monoclinic, space group P21/n (No. 14, a, 14.374(6) Å, b, 24.425(10) Å, c, 22.097(10) Å, β, 102.66(4)°, V, 7569(6) Å3, Z, 4, T, 123 K, R, 0.0540 [I > 2σ(I, Rw, 0.1462 (all data, GOF on F2, 1.035 all data, CCDC reference number 612136
    • 2 = 1.035 (all data), CCDC reference number 612136.
  • 23
    • 0034742975 scopus 로고    scopus 로고
    • The common Rh-Rh bond lengths in Rh cluster complexes are ca. 2.75 Å. For instance, see: Farrar, D. H.; Grachova, E. V.; Lough, A.; Patirana, C.; Poë, A. J.; Tunik, S. P. J. Chem. Soc., Dalton Trans. 2001, 2015.
    • The common Rh-Rh bond lengths in Rh cluster complexes are ca. 2.75 Å. For instance, see: Farrar, D. H.; Grachova, E. V.; Lough, A.; Patirana, C.; Poë, A. J.; Tunik, S. P. J. Chem. Soc., Dalton Trans. 2001, 2015.
  • 25
    • 33846599331 scopus 로고    scopus 로고
    • The trans conformation of 4 was also confirmed by the X-ray analysis.
    • The trans conformation of 4 was also confirmed by the X-ray analysis.
  • 26
    • 33846570928 scopus 로고    scopus 로고
    • The DFT calculations were performed on a model compound, where all the meso substituents were replaced by hydrogen atoms. The model compound was optimized at B3LYP/LANL2DZ for Rh and at 3-21.G* for the rest, and the natural population analysis was achieved at the same level. For orbital analysis, the single-point calculation at B3LYP/LANL2DZ for Rh and at 6-31.G** for the rest was adopted.
    • The DFT calculations were performed on a model compound, where all the meso substituents were replaced by hydrogen atoms. The model compound was optimized at B3LYP/LANL2DZ for Rh and at 3-21.G* for the rest, and the natural population analysis was achieved at the same level. For orbital analysis, the single-point calculation at B3LYP/LANL2DZ for Rh and at 6-31.G** for the rest was adopted.
  • 28
    • 33846641214 scopus 로고    scopus 로고
    • Cotton, F. A, Murillo, C. A, Walton, R. A, Eds, 3rd ed, Springer Science and Business Media, Inc, New York
    • Cotton, F. A., Murillo, C. A., Walton, R. A., Eds. Multiple Bonds between Metal Atoms, 3rd ed.; Springer Science and Business Media, Inc.: New York, 2005.
    • (2005) Multiple Bonds between Metal Atoms


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.