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Volumn 45, Issue 10, 2006, Pages 3852-3854

Bis[iridium(I)] complex of inverted N-confused porphyrin

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM; ORGANOMETALLIC COMPOUND; PORPHYRIN;

EID: 33646936086     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060203+     Document Type: Article
Times cited : (50)

References (24)
  • 13
    • 0039874060 scopus 로고
    • In the case of similar iridium(I) carbonyl complexes bearing normal porphyrinato ligands, gradual photodecomposition was observed. (a) Ogoshi, H.; Setune, J.; Yoshida, J. J. Organomet. Chem. 1978, 159, 317.
    • (1978) J. Organomet. Chem. , vol.159 , pp. 317
    • Ogoshi, H.1    Setune, J.2    Yoshida, J.3
  • 15
    • 33646942013 scopus 로고    scopus 로고
    • note
    • 2 = 0.935 (all data), CCDC reference number 293083.
  • 18
    • 33646934789 scopus 로고    scopus 로고
    • note
    • 1H NMR signals were similar to those of 2, and the absorption spectrum of the mixture closely resembled that of 2. Hence, the mixture consisted of A and its isomer with different coordination sites of the inner Ir atom.
  • 19
    • 33646916721 scopus 로고    scopus 로고
    • note
    • All of the calculations were performed by a B3LYP method with a Gaussian03 program package. For structural optimizations, the LANL2DZ basis set was used for Ir and the 6-31G** basis sets were used for the other atoms. The NMR calculations were achieved with GIAO method, where the LANL2DZ basis set was used for Ir and the 6-311++G** basis sets were used for the other atoms.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.