Synthesis and X-ray Crystallography of Rh(I) Carbonyl Complexes of Amethyrin

Inorganic Chemistry

Volumn 37, Issue 8, 1998, Pages 2073-2076

  Sessler, Jonathan L ^a   Gebauer, Andreas ^a   Guba, Anka ^a   Scherer, Markus ^a   Lynch, Vincent ^a  

^a The University of Texas at Austin   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000455406     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971018m     Document Type: Article

References (15)

1. Sessler, J. L.; Weghorn, S. J.; Hiseada, Y.; Lynch, V. Chem. - Eur. J. 1995, 1, 56.
2. Weghorn, S. J.; Sessler, J. L.; Lynch, V.; Baumann, T. F.; Sibert, J. W. Inorg. Chem. 1996, 35, 1089.
3. Sessler, J. L.; Burrell, A. K.; Lisowski, J.; Gebauer, A.; Cyr, M. J.; Lynch, V. Bull. Soc. Chim. Fr. 1996, 133, 725.
4. (a) Takenaka, A.; Sasada, Y. J. Chem. Soc., Chem. Commun. 1973, 792.
5. (b) Takenaka, A.; Sasada, Y.; Ogoshi, H.; Omura, T.; Yoshida, Z.-I. Acta Crystallogr. 1973, B31, 1.
6. (c) Brothers, P. J.; Collman, J. P. Acc. Chem. Res. 1986, 19, 209.
7. Burrell, A. K.; Sessler, J. L.; Cyr, M. J.; McGhee, E.; Ibers, J. A. Angew. Chem., Int. Ed. Engl. 1991, 30, 91.
8. A bowl-like structure with cis coordination of the metal center has been observed previously in the case of another nonaromatic expanded porphyrin-rhodium(I) complex, This system, in contradistinction from the present work, involved a ligand that was not fully conjugated; see the following: Carré, F. H.; Corriu, R. J. P.; Bolin, G.; Moreau, J. J. E.; Vernhet, C. Organometallics 1993, 12, 2478.
9. Bondi, A. J. Phys. Chem. 1964, 68, 441.
10. Holleman, A. F., Wiberg, N., Eds. Lehrbuch der Anorganischen Chemie; Walter de Gruyter: Berlin, 1985; p 1198.
11. 1H NMR spectrum. This is consistent with the rate of cis/trans isomer interconversion being faster in this solvent.
12. 1H NMR analyses could not be carried out effectively due to lack of sample.
13. Sheldrick, G. M. SHELXTL/PC (Version 5.03); Siemens Analytical X-ray Instruments, Inc.: Madison, WI, 1994.
14. International Tables for X-ray Crystallography: Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Boston, 1992; Vol. C, Tables 4.2.6.8 and 6.1.1.4.
15. Gadol, S. M.; Davis, R. E. Organometallics 1982, 1, 1607-1613.