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2 had been synthesized and characterized: Gelalcha, F. G.; Schulz, M.; Kluge, R.; Sieler, J.-J. Chem. Soc., Dalton Trans. 2002, 2517-2521.
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2 had been synthesized and characterized: Gelalcha, F. G.; Schulz, M.; Kluge, R.; Sieler, J.-J. Chem. Soc., Dalton Trans. 2002, 2517-2521.
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Weissberg, A.1
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27
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33846176922
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All attempts to crystallize complexes 5 and 6 using different solvent mixtures gave rise to crystals of complexes 3 and 4, respectively.
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All attempts to crystallize complexes 5 and 6 using different solvent mixtures gave rise to crystals of complexes 3 and 4, respectively.
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28
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33846153808
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Crystal data for 1: orthorhombic, space group P2 12121; a, 9.7853-(2) Å, b, 29.5192(6) Å, c, 34.7622(7) Å; 2[Cu4I 4(iPr-pybox)2]· hexane, Z, 4; R(F02, 0.0424 and R w(F02, 0.1021; Absolute structure parameter, 0.011(4, For 2: trigonal, space group P3 2; a, b, 11.74400(10) Å, c, 23.9252(2) Å, Z, 3; R(F02, 0.0511 and Rw(F02, 0.1330; Absolute structure parameter, 0.017(19, For 3: monoclinic, space group P21; a, 12.0991(4) Å, b, 16.7041-(6) Å; c, 13.6704(4, β, 113.575(2)°; [Cu 2{(R,R)-Ph-pybox}2, PF
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2) = 0.1833; Absolute structure parameter = 0.03(4).
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30
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33846165498
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5.
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5.
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31
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33845280842
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(a) Cotton, F. A.; Feng, X.; Matusz, M.; Poli, R. J. Am. Chem. Soc. 1988, 110, 7077.
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33846157457
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-1).
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-1).
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35
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0006977075
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(b) Blackburn, N. J.; Karlin, K. D.; Concannon, M.; Hayes, J. C.; Gultneh, Y.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1984, 939-940.
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0141923179
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Hu, X.1
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Meyer, K.3
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37
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33846138693
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11a
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11a
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38
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33846143565
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For example, see: ref 13 (coordination of alkynyl and imine groups in the synthesis of propargylamines) and ref 11 coordination of benzoate and alkene groups in the allylic oxidation of olefins
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For example, see: ref 13 (coordination of alkynyl and imine groups in the synthesis of propargylamines) and ref 11 (coordination of benzoate and alkene groups in the allylic oxidation of olefins.
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