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20344391794
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See Supporting Information for details.
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See Supporting Information for details.
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19
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20344363281
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note
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Nonlinear effects in mixed-ligand systems are certainly possible and are under investigation.
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20
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20344390628
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note
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2NEt. The resulting solution was stored at 0-4°C for 24 h. The solvent was removed and the mixture was analyzed without purification to determine kinetic selectivity. When desired, pure components were obtained by silica gel column chromatography, eluting with hexanes to recover the azide and with a 10:1 hexanes:EtOAc to elute the product (14). Values of enantiomeric excess were determined by HPLC using a Chiralcel OD-H column
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33751385202
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A.S. Thompson, G.R. Humphrey, A.M. DeMarco, D.J. Mathre, and E.J.J. Grabowski J. Org. Chem. 58 1993 5886 5888
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11844255741
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