Synthesis of molybdenum complexes that contain "hybrid" triamidoamine ligands, [(hexaisopropylterphenyl-NCH2CH 2)2NCH2CH2N-aryl]3-, and studies relevant to catalytic reduction of dinitrogen

Inorganic Chemistry

Volumn 45, Issue 23, 2006, Pages 9185-9196

  Weare, Walter W ^a   Schrock, Richard R ^a   Hock, Adam S ^a   Müller, Peter ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; ETHYLENEDIAMINE DERIVATIVE; LIGAND; MOLYBDENUM; NITROGEN; TERPHENYL DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; X RAY CRYSTALLOGRAPHY;

AMMONIA; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; ETHYLENEDIAMINES; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; MOLYBDENUM; NITROGEN; OXIDATION-REDUCTION; TERPHENYL COMPOUNDS;

EID: 33751297068     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0613457     Document Type: Article

References (42)

1. (a) Schrock, R. R. Acc. Chem. Res. 1997, 30, 9.
2. (b) Greco, G. E.; Schrock, R. R. Inorg. Chem. 2001, 40, 3850.
3. (c) Greco, G. E.; Schrock, R. R. Inorg. Chem. 2001, 40, 3861.
4. (d) O'Donoghue, M. B.; Davis, W. M.; Schrock, R. R. Inorg. Chem. 1998, 37, 5149.
5. Dobbs, D. A.; Schrock, R. R.; Davis, W. M. Inorg. Chim. Acta 1997, 36, 171.
6. Greco, G. E.; O'Donoghue, M. B.; Seidel, S. W.; Davis, W. M.; Schrock, R. R. Organometallics 2000, 19, 1132.
7. (a) Yandulov, D. V.; Schrock, R. R. Science 2003, 301, 76.
8. (b) Yandulov, D. V.; Schrock, R. R. Inorg. Chem. 2005, 44, 1103.
9. (c) Yandulov, D. V.; Schrock, R. R. Can. J. Chem. 2005, 83, 341.
10. Schrock, R. R. Acc. Chem. Res. 2005, 38, 955.
11. Ritleng, V.; Yandulov, D. V.; Weare, W. W.; Schrock, R. R.; Hock, A. R.; Davis, W. M. J. Am. Chem. Soc. 2004, 126, 6150.
12. Weare, W. W.; Dai, C.; Byrnes, M. J.; Chin, J.; Schrock, R. R. Proc. Nat. Acad. Sci. in press.
13. (a) Wolfe, J. P.; Wagaw, S.; Marcoux, J.-F.; Buchwald, S. L. Acc. Chem. Res. 1998, 31, 805.
14. (b) Hartwig, J. Acc. Chem. Res. 1998, 31, 852.
15. (a) Lehnert, N.; Tuczek, F. Inorg. Chem. 1999, 38, 1659.
16. (b) Lehnert, N.; Tuczek, F. Inorg. Chem. 1999, 38, 1671 and references therein.
17. (a) Burgess, B. K.; Lowe, D. J. Chem. Rev. 1996, 96, 2983.
18. (b) Hardy, R. W. F.; Bottomley, F.; Burns, R. C. A Treatise on Dinitrogen Fixation; Wiley-Interscience: New York, 1979.
19. (c) Veeger, C.; Newton, W. E., Advances in Nitrogen Fixation Research; Dr. W. Junk/Martinus Nijhoff: Boston, 1984.
20. (d) Coughlan, M. P. Molybdenum and Molybdenum-Containing Enzymes; Pergamon: New York, 1980.
21. (a) Rees, D. C.; Howard, J. B. Curr. Opin. Chem. Biol. 2000, 4, 559.
22. (b) Bolin, J. T.; Ronco, A. E.; Morgan, T. V.; Mortenson, L. E.; Xuong, L. E. Proc. Natl. Acad. Sci. 1993, 90, 1078.
23. (c) Kim, J.; Rees, D. C. Science 1992, 257, 1677.
24. Einsle, O.; Tezcan, F. A.; Andrade, S. L. A.; Schmid, B.; Yoshida, M.; Howard, J. B.; Rees, D. C. Science 2002, 297, 1696.
25. The only other known systems that will catalytically reduce dinitrogen are those discovered by Shilov (Shilov, A. E. Russ. Chem. Bull. Int. Ed. 2003, 52, 2555). These systems require Mo and are catalytic with respect to Mo, but they reduce dinitrogen to a mixture of hydrazine and ammonia (∼10:1). The reaction is run in methanol in the presence of magnesium hydroxide and a strong reducing agent such as sodium amalgam. Few mechanistic details are known.
26. (a) Eady, R. R. Chem. Rev. 1996, 96, 3013.
27. (b) Smith, B. E. Adv. Inorg. Chem. 1999, 47, 159.
28. (c) Rehder, D. Coord. Chem. Rev. 1999, 182, 297.
29. (a) Brown, S. D.; Peters, J. C. J. Am. Chem. Soc. 2005, 127, 1913.
30. (b) Brown, S. D.; Peters, J. C. J. Am. Chem. Soc. 2004, 126, 4538.
31. (c) Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2004, 126, 6252.
32. (d) Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 10782.
33. (e) Smith, J. M.; Sadique, A. R.; Cundari, T. R.; Rodgers, K. R.; Lukat-Rodgers, G.; Lachicotte, R. J.; Flaschenriem, C. J.; Vela, J.; Holland, P. L. J. Am. Chem. Soc. 2006, 128, 756.
34. (f) Holland, P. L. Can. J. Chem. 2005, 83, 296.
35. (g) Smith, J. M.; Lachicotte, R. J.; Holland, P. L. J. Am. Chem. Soc. 2003, 125, 15752.
36. (h) Smith, J. M.; Lachicotte, R. J.; Holland, P. L. J. Am. Chem. Soc. 2003, 125, 15752.
37. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518.
38. Yandulov, D. V.; Schrock, R. R. J. Am Chem. Soc. 2002, 124, 6252.
39. Yandulov, D. V.; Schrock, R. R.; Rheingold, A. L.; Ceccarelli, C.; Davis, W. M. Inorg. Chem. 2003, 42, 796.
40. Talik, T.; Talik, Z.; Ban-Oganowska, H. Synthesis 1974, 293.
41. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467.
42. Sheldrick, G. M. SHELXL 97; University of Göttingen: Göttingen, Germany, 1997.