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33751248083
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note
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For methanolysis carried out on structurally related compounds, see Ref [18].
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47
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33751245748
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note
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2).
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48
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33751227061
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note
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A control experiment carried out on an enantioenriched sample of 12 (ee not determined) revealed the presence of four products and allowed us to distinguish unambiguously the signals corresponding to the meso/dl pair from the ones corresponding to the E and Z isomers.
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49
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33751253942
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note
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Mass spectrometry of the crude mixture revealed the presence of trace amounts of a product that might correspond to deprotected and oxidised analogues of the desired product.
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53
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2942622224
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Trace amounts of (E)-dodec-1-enyl(ethyl)phenylphosphine borane, ethyl(phenyl)vinyl-phosphine borane and diethyl(phenyl)phosphine borane were detected in the crude reaction mixture, accounting only partially for the low overall yield of the desymmetrisation process; for reductive pathway involving structurally related unsaturated phosphines, see:
-
Trace amounts of (E)-dodec-1-enyl(ethyl)phenylphosphine borane, ethyl(phenyl)vinyl-phosphine borane and diethyl(phenyl)phosphine borane were detected in the crude reaction mixture, accounting only partially for the low overall yield of the desymmetrisation process; for reductive pathway involving structurally related unsaturated phosphines, see:. Shapland P., and Vedejs E. J. Org. Chem. 69 (2004) 4094-4100
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