Characterization of phosphorylated cross-linked resistant starch by 31P nuclear magnetic resonance (31P NMR) spectroscopy

Carbohydrate Polymers

Volumn 67, Issue 2, 2007, Pages 201-212

  Sang, Yijun ^a   Prakash, Om ^a   Seib, Paul A ^a  

^a KANSAS STATE UNIVERSITY   (United States)

Author keywords

31P NMR spectroscopy; Distarch monophosphate; Monostarch monophosphate; Phosphorylated resistant starch

Indexed keywords

CROSSLINKING; ESTERS; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLICS; PH EFFECTS;

ORGANOPHOSPHATES; PHOSPHATE ESTERS; SODIUM TRIMETAPHOSPHATE; SODIUM TRIPOLYPHOSPHATE;

STARCH;

TRITICUM AESTIVUM;

EID: 33750989048     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2006.05.009     Document Type: Article

References (33)

1. AACC. (2000). Approved Methods of the AACC, 10th ed. The Association: St Paul, MN.
2. AOAC. (2000). Approved Methods of the AOAC, 17th ed. Method 991.43. Total dietary fiber enzymatic gravimetric method. First action. 1992. The Association: Gaithersburg, MD.
3. Barany M., and Glonek T. Phosphorus-31 nuclear magnetic resonance of contractile systems. Methods in Enzymology Vol. 85 (1982), Academic Press 624-676
4. Briggs D.R., and Hanig M. Chemical state of phosphorus in starch as indicated by titration curves on electrodialyzed starches. Cereal Chemistry 23 3 (1946) 277-287
5. CFR (Code of Federal Regulations) (1995). Food starch modified. In Food Additives Permitted in Food for Human Consumption, Title 21, Chapter 1, Part 172, section 172.892. US Government Printing Office, Washington.
6. Cook W.H., Lipkin D., and Markham R. The formation of a cyclic dianhydrodiadenylic acid by the alkalin degradation of adenosine-5′-triphosphoric acid. Journal of American Chemistry Society 79 (1957) 3607-3608
7. EEC (2000). Official Journal of European Communities 30.10.2000, L277, pp52-59.
8. Englyst H.N., Kingman S.M., and Cummings J.H. Classification and measurement of nutritionally important starch fractions. European Journal of Clinical Nutrition (1992) S33-S50
9. Felton, G. F., & Schopmeyer, H. H. (1943). Thick-bodied starch and method of making. US patent 2,328,537.
10. Friess S.L. Rates and energetics of activation of the acid-catalyzed hydrolysis of adenosine triphosphate. Journal of American Chemistry Society 75 (1953) 323-326
11. Gramera R.E., Heerema J., and Parrish F.W. Distribution and structural form of phosphate ester groups in commercial starch phosphates. Cereal Chemistry 43 (1966) 104-111
12. 31P nuclear magnetic resonance spectroscopy. Cereal Chemistry 73 (1996) 702-707
13. Kerr, R. W., & Cleveland, F. C. (1957). Process for the preparation of distarch phosphate and the resulting product. US Patent 2, 801,242.
14. Koch V.H., Bommer H.D., and Kleve J.K. Analytical investigations on phosphate cross-linked starches. Starch/Starke 34 (1982) 16-21
15. Inoue H., Tone N., Nakayama H., and Tsuhako M. Stereoselective phosphorylation of branched cyclodextrins with inorganic cyclo-triphosphate. Carbohydrate Research 338 (2003) 2067-2074
16. Lammers G., Stamhuis E.J., and Beenackers A.C.M. Kinetics of the hydroxypropylation of potato starch in aqueous solution. Industrial and Engineering Chemistry Research 32 (1993) 835-842
17. Lim S., and Seib P.A. Preparation and pasting properties of wheat and corn starch phosphates. Cereal Chemistry 70 2 (1993) 137-144
18. Lipkin D., Markham R., and Cook W.H. The degradation of adenosin-5′-triphosphoric acid (ATP) by means of aqueous barium hydroxide. Journal of American Chemistry Society 81 (1959) 6075-6080
19. Matsunaga N., and Seib P.A. Extraction of wheat starch with aqueous sodium hydroxide. Cereal Chemistry 74 6 (1997) 851-857
20. Miller D.L., and Westheimer F.H. The hydrolysis of γ-phenylpropyl di- and triphosphates. Journal of American Chemistry Society 88 (1966) 1507-1511
21. Mitchell W.A. Analyzing the metaphosphate stabilization reaction of starch by acid titration. Food Technology 26 (1972) 34-43
22. Roberts S.B. High-glycemic index foods, hunger and obesity: is there a connection. Nutrition Reviews 58 6 (2000) 163-169
23. Smith R.J., and Caruso J. Determination of phosphorus. Methods in Carbohydrate Chemistry 4 (1964) 42-46
24. Sojka S.A., and Wolfe R.A. Analysis of commercial sodium tripolyphosphates by phosphorus-31 Fourier transform nuclear magnetic resonance spectrometry. Analytical Chemistry 50 (1978) 585-587
25. Tarelli E., Lemercinier X., and Wheeler S. Direct preparation of cyclodextrin monophosphates. Carbohydrate Research 302 (1997) 27-34
26. Topping D.L., and Clifton P.M. Short-chain fatty acids and human colonic function: roles of resistant starch and nonstarch polysaccharides. Physiological Review 81 3 (2001) 1031-1064
27. Tsuhako M., Nakajima A., Miuajima T., Ohashi S., Nariai H., and Motooka I. The reaction of cyclo-triphosphate with l-α or β-Alanine. Bulletin of the Chemical Society of Japan 58 (1985) 3092-3098
28. Van der Burgt Y.E.M., Bergsma J., Bleeker I.P., Mijland P.J.H.C., Kamerling J.P., and Vliegenthart J.F.G. Distribution of methyl substituents over branched and linear regions in methylated starches. Carbohydrate Research 312 (1998) 201-208
29. Vonk R.J., Hagedoorn R.E., Graaff R., Elzinga H., Tabak S., Yang Y.X., and Stellaard F. Digestion of so-called resistant starch sources in the human small intestine. American Journal of Clinical Nutrition 72 (2000) 432-438
30. Warren J.M., Henry C.J.K., and Simonite V. Low glycemic index breakfast and reduced food intake in preadolescent children. Pediatrics 112 5 (2003) 1174-1175
31. Whitaker J.R. Principles of Enzymology for the Food Sciences. 2nd ed. (1972), Marcel Dekker, New York 406-407
32. Woo K., and Seib P.A. Cross-linking of wheat starch and hydroxypropylated wheat starch in alkaline slurry with sodium trimetaphosphate. Carbohydrate Polymers 33 (1997) 263-271
33. Woo K., and Seib P.A. Crosslinked resistant starch: preparation and properties. Cereal Chemistry 79 6 (2002) 819-825