Me-AnilaPhos: a new chiral phosphine-phosphoramidite ligand for a highly efficient Rh-catalyzed asymmetric olefin hydrogenation

Tetrahedron Letters

Volumn 47, Issue 45, 2006, Pages 7947-7950

  Vallianatou, Kalliopi A ^a   Kostas, Ioannis D ^a   Holz, Jens ^b   Börner, Armin ^b,c  

^a INSTITUTE OF BIOLOGY   (Greece)

^b LEIBNIZ INSTITUT FÜR KATALYSE E V AN DER UNIVERSITÄT ROSTOCK   (Germany)

^c UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

Asymmetric hydrogenation; BINOL; Chiral ligand; Homogeneous catalysis; Phosphine; Phosphoramidite

Indexed keywords

2 DIPHENYLPHOSPHINO N METHYLANILINE; 2,2' DIHYDROXY 1,1' BINAPHTHYL; ALKENE; ANILINE DERIVATIVE; CINNAMIC ACID DERIVATIVE; DICHLOROMETHANE; DIMETHYL ITACONATE; HYDROGEN; ITACONIC ACID; METHANOL; METHYL ALPHA ACETAMIDOCINNAMATE; PHOSPHINE; PHOSPHORAMIDOUS ACID; RHODIUM COMPLEX; SOLVENT; UNCLASSIFIED DRUG;

AMBIENT AIR; ARTICLE; CATALYSIS; CATALYST; CHIRALITY; COMPLEX FORMATION; ENANTIOSELECTIVITY; HYDROGENATION; ROOM TEMPERATURE; STATISTICAL SIGNIFICANCE; SYNTHESIS;

EID: 33749238512     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.08.136     Document Type: Article

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45. 4a
46. 3): δ -22.2 (s).
47. 2: C, 77.35; H, 4.83; N, 2.31%. Found: C, 76.94; H, 5.15; N, 2.38%.
48. 2Rh: C, 62.48; H, 4.57; N, 1.55%. Found: C, 61.91; H, 4.95; N, 1.97%.
49. 1H NMR. Configurations were assigned by comparison with the retention time of a known enantiomer.