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Volumn 128, Issue 38, 2006, Pages 12582-12588

One-electron reduction of kinetically stabilized dipnictenes: Synthesis of dipnictene anion radicals

Author keywords

[No Author keywords available]

Indexed keywords

CYCLIC VOLTAMMETRY; ELECTRONS; RAMAN SPECTROSCOPY; REDOX REACTIONS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

EID: 33749171575     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja064062m     Document Type: Article
Times cited : (118)

References (57)
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    • Weber, L.1
  • 10
    • 33845550118 scopus 로고
    • A number of theoretical calculations (ab initio and semiempirical) for diphosphenes have been reported. For examples, see: (a) Yoshifuji, M.; Shibayama, K.; Inamoto, N. J. Am. Chem. Soc. 1983, 105, 2495.
    • (1983) J. Am. Chem. Soc. , vol.105 , pp. 2495
    • Yoshifuji, M.1    Shibayama, K.2    Inamoto, N.3
  • 39
    • 0036025403 scopus 로고    scopus 로고
    • B3LYP was selected as a calculation method because the EA values calculated by the DFT method for several examples of atoms and molecules containing heavier main group elements are known to be in excellent agreement with the corresponding experimental data: see: Rienstra-Kiracofe, J. C.; Tschumper, G. S.; Schaefer, H. F.; Nandi, S.; Ellison, G. B. Chem. Rev. 2002, 102, 231.
    • (2002) Chem. Rev. , vol.102 , pp. 231
    • Rienstra-Kiracofe, J.C.1    Tschumper, G.S.2    Schaefer, H.F.3    Nandi, S.4    Ellison, G.B.5
  • 42
    • 33749176750 scopus 로고    scopus 로고
    • note
    • The integrals of the overlap of the valence p Orbitals were calculated at HF/STO-3G for H:ECP(lan12mb) for E with the optimized structures calculated at B3LYP/6-31G(d) for H:ECP|TZ(2d)+diffuse] for the P, As, Sb, and Bi levels.
  • 43
    • 33749185818 scopus 로고    scopus 로고
    • note
    • .-], it should be satisfactorily isolated because a number of single crystals suitable for X-ray crystallographic analysis were obtained.
  • 44
    • 0041678344 scopus 로고
    • To our knowledge, there is no paper on the observation of organoantimony radicals by ESR spectroscopy, except for the observation of the radical species of the antimony-containing conjugated systems and the inorganic antimony compounds; See: (a) Colussi, A. J.; Morton, J. R.; Preston, K. F. J. Phys. Chem. 1975, 79, 1855.
    • (1975) J. Phys. Chem. , vol.79 , pp. 1855
    • Colussi, A.J.1    Morton, J.R.2    Preston, K.F.3
  • 45
    • 4243496587 scopus 로고
    • (b) Alberti, A.; Hudson, A. J. Organomet. Chem. 1979, 182, C49. Therefore, no straightforwardly helpful information could be obtained for the detailed analysis of the ESR spectra observed in this work.
    • (1979) J. Organomet. Chem. , vol.182
    • Alberti, A.1    Hudson, A.2
  • 47
    • 33749171200 scopus 로고    scopus 로고
    • note
    • max for the BbtE=EBbt systems in hexane by the calculations at the same level. See Supporting Information.
  • 55
    • 0004133516 scopus 로고    scopus 로고
    • Gaussian, Inc.: Pittsburgh, PA
    • Frisch, M. J. et al. Gaussian 98; Gaussian, Inc.: Pittsburgh, PA, 1998.
    • (1998) Gaussian 98
    • Frisch, M.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.