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33749176750
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The integrals of the overlap of the valence p Orbitals were calculated at HF/STO-3G for H:ECP(lan12mb) for E with the optimized structures calculated at B3LYP/6-31G(d) for H:ECP|TZ(2d)+diffuse] for the P, As, Sb, and Bi levels.
-
-
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43
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33749185818
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note
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.-], it should be satisfactorily isolated because a number of single crystals suitable for X-ray crystallographic analysis were obtained.
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44
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0041678344
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To our knowledge, there is no paper on the observation of organoantimony radicals by ESR spectroscopy, except for the observation of the radical species of the antimony-containing conjugated systems and the inorganic antimony compounds; See: (a) Colussi, A. J.; Morton, J. R.; Preston, K. F. J. Phys. Chem. 1975, 79, 1855.
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max for the BbtE=EBbt systems in hexane by the calculations at the same level. See Supporting Information.
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