Sterically encumbered diphosphaalkenes and a bis(diphosphene) as potential multiredox-active molecular switches: EPR and DFT investigations

Inorganic Chemistry

Volumn 42, Issue 20, 2003, Pages 6241-6251

  Dutan, Cosmina ^a   Shah, Shashin ^b   Smith, Rhett C ^b   Choua, Sylvie ^a   Berclaz, Théo ^a   Geoffroy, Michel ^a   Protasiewicz, John D ^b  

^a UNIVERSITY OF GENEVA   (Switzerland)

^b CASE WESTERN RESERVE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; AROMATIC COMPOUND; BIS(DIPHOSPHENE); LIGAND; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CONFORMATION; DENSITY; ELECTRON SPIN RESONANCE; MAGNETISM; MOLECULAR INTERACTION; MOLECULAR MODEL; OXIDATION REDUCTION REACTION; STEREOCHEMISTRY; THEORY;

EID: 0141566518     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic030079j     Document Type: Article

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55. .-) are fixed and the other parameters are allowed to relax.
56. -1).
57. 2- (0°) are therefore compatible with the spectra but not required.