Synthesis of bis(2,6-dimesityl-4-methylphenyl)phosphaarsene and EPR of its radical anion

Chemistry Letters

Volumn , Issue 9, 1997, Pages 855-856

  Tsuji, Kyoko ^a   Fujii, Yuuichi ^a   Sasaki, Shigeru ^a   Yoshifuji, Masaaki ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031314083     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.855     Document Type: Article

References (23)

1. M. Yoshifuji, I. Shima, N. Inamoto, K. Hirotsu, and T. Higuchi, T. J. Am. Chem. Soc., 103, 4587 (1981); 104, 6167 (1982); "Multiple Bonds and Low Coordination in Phosphorus Chemistry;" ed by M. Regitz and O. J. Scherer, Georg Thieme Verlag, Stuttgart (1990).
2. M. Yoshifuji, I. Shima, N. Inamoto, K. Hirotsu, and T. Higuchi, T. J. Am. Chem. Soc., 103, 4587 (1981); 104, 6167 (1982); "Multiple Bonds and Low Coordination in Phosphorus Chemistry;" ed by M. Regitz and O. J. Scherer, Georg Thieme Verlag, Stuttgart (1990).
3. M. Yoshifuji, I. Shima, N. Inamoto, K. Hirotsu, and T. Higuchi, T. J. Am. Chem. Soc., 103, 4587 (1981); 104, 6167 (1982); "Multiple Bonds and Low Coordination in Phosphorus Chemistry;" ed by M. Regitz and O. J. Scherer, Georg Thieme Verlag, Stuttgart (1990).
4. L. Weber and U. Sonnenberg, Chem. Ber., 122, 1809 (1989); A. H. Cowley, J. G. Lasch, N. C. Norman, and M. Pakulski, J. Am. Chem. Soc., 105, 5506 (1983).
5. L. Weber and U. Sonnenberg, Chem. Ber., 122, 1809 (1989); A. H. Cowley, J. G. Lasch, N. C. Norman, and M. Pakulski, J. Am. Chem. Soc., 105, 5506 (1983).
6. C.-J. F. Du, H. Hart, and K.-K. D. Ng, J. Org. Chem., 51, 3162 (1986).
7. X. He, M. M. Olmstead, and P. P. Power, J. Am. Chem. Soc., 114, 9668 (1992); J. J. Ellison, K. Ruhlandt-Senge, and P. P. Power, Angew. Chem., Int. Ed. Engl., 33, 1178 (1994); S. Simons, L. Pu, M. M. Olmstead, and P. P. Power, Organometallics, 16, 1920 (1997)
8. X. He, M. M. Olmstead, and P. P. Power, J. Am. Chem. Soc., 114, 9668 (1992); J. J. Ellison, K. Ruhlandt-Senge, and P. P. Power, Angew. Chem., Int. Ed. Engl., 33, 1178 (1994); S. Simons, L. Pu, M. M. Olmstead, and P. P. Power, Organometallics, 16, 1920 (1997)
9. X. He, M. M. Olmstead, and P. P. Power, J. Am. Chem. Soc., 114, 9668 (1992); J. J. Ellison, K. Ruhlandt-Senge, and P. P. Power, Angew. Chem., Int. Ed. Engl., 33, 1178 (1994); S. Simons, L. Pu, M. M. Olmstead, and P. P. Power, Organometallics, 16, 1920 (1997)
10. 3) δ = 161.2.
11. 2+1, 100).
12. 3) δ = 492.7. Attempted isolation of the corresponding diarsene has not been successful so far.
13. 3) δ = 492.7. Attempted isolation of the corresponding diarsene has not been successful so far.
14. 54AsP: C, 78.93; H, 7.15%.
15. L. Weber, D. Bungardt, U. Sonnenberg, and R. Boese, Angew. Chem., Int. Ed. Engl., 27, 1537 (1988); J. Escudie, C. Couret, H. Ranaivonjatovo, and J.-G. Wolf, Tetrahedron Lett., 24, 3625 (1983); C. N. Smit, M. Nemansky, and F. Bickelhaupt, Phosphorus and Sulfur, 30, 806 (1987); P. Jutzi and U. Meyer, Chem. Ber., 121, 559 (1988).
16. L. Weber, D. Bungardt, U. Sonnenberg, and R. Boese, Angew. Chem., Int. Ed. Engl., 27, 1537 (1988); J. Escudie, C. Couret, H. Ranaivonjatovo, and J.-G. Wolf, Tetrahedron Lett., 24, 3625 (1983); C. N. Smit, M. Nemansky, and F. Bickelhaupt, Phosphorus and Sulfur, 30, 806 (1987); P. Jutzi and U. Meyer, Chem. Ber., 121, 559 (1988).
17. L. Weber, D. Bungardt, U. Sonnenberg, and R. Boese, Angew. Chem., Int. Ed. Engl., 27, 1537 (1988); J. Escudie, C. Couret, H. Ranaivonjatovo, and J.-G. Wolf, Tetrahedron Lett., 24, 3625 (1983); C. N. Smit, M. Nemansky, and F. Bickelhaupt, Phosphorus and Sulfur, 30, 806 (1987); P. Jutzi and U. Meyer, Chem. Ber., 121, 559 (1988).
18. L. Weber, D. Bungardt, U. Sonnenberg, and R. Boese, Angew. Chem., Int. Ed. Engl., 27, 1537 (1988); J. Escudie, C. Couret, H. Ranaivonjatovo, and J.-G. Wolf, Tetrahedron Lett., 24, 3625 (1983); C. N. Smit, M. Nemansky, and F. Bickelhaupt, Phosphorus and Sulfur, 30, 806 (1987); P. Jutzi and U. Meyer, Chem. Ber., 121, 559 (1988).
19. bcn,Z = 4, a = 21.970(4), b = 8.29(1), c = 23.329(5) Å, V = 4246(5) Å3.
20. A.-M. Caminade, M. Verrier, C. Ades, N. Paillons, and M. Koenig, J. Chem. Soc., Chem. Commun., 1984, 875.
21. M. Yoshifuji, T. Sato, and N. Inamoto, Chem. Lett., 1988, 1735.
22. M. Culcasi, G. Gronchi, J. Escudié, C. Couret, L. Pujol, and P. Tordo, J. Am. Chem. Soc., 108, 3130 (1986); A. J. Bard, A. H. Cowley, J. E. Kilduff, J. K. Leland, N. C. Norman, M. Pakulski, and G. A. Heath, J. Chem. Soc., Dalton Trans., 1987, 249.
23. M. Culcasi, G. Gronchi, J. Escudié, C. Couret, L. Pujol, and P. Tordo, J. Am. Chem. Soc., 108, 3130 (1986); A. J. Bard, A. H. Cowley, J. E. Kilduff, J. K. Leland, N. C. Norman, M. Pakulski, and G. A. Heath, J. Chem. Soc., Dalton Trans., 1987, 249.