Metal-complex-bearing star polymers by metal-catalyzed living radical polymerization: Synthesis and characterization of poly(methyl methacrylate) star polymers with Ru(II)-embedded microgel cores

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 44, Issue 17, 2006, Pages 4966-4980

  Terashima, Takaya ^a   Ouchi, Makoto ^a   Ando, Tsuyoshi ^a   Kamigaito, Masami ^b   Sawamoto, Mitsuo ^a  

^a KYOTO UNIVERSITY   (Japan)

^b NAGOYA UNIVERSITY   (Japan)

Author keywords

Living polymerization; Microgel core; Polymer catalyst; Polymer linking; Radical polymerization; Ruthenium complex; Star polymers

Indexed keywords

CATALYSIS; FREE RADICAL POLYMERIZATION; GELS; LIVING POLYMERIZATION; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

MICROGEL CORE; POLYMER CATALYSTS; POLYMER LINKING; RADICAL POLYMERIZATION; RUTHENIUM COMPLEX; STAR POLYMERS;

POLYMERS;

EID: 33748530599     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.21597     Document Type: Conference Paper

References (33)

1. For reviews on the synthesis of star polymers by cationic living polymerization, see (a) Sawamoto, M. In Cationic Polymerization; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; pp 412-420;
2. (b) In new methods of Polymer Synthesis Sawamoto, M.; Kamigaito, M. In New Methods of Polymer Synthesis; Ebdon, J. R.; Eastmond, G. C., Eds.; Blackie: Glasgow, 1995; Vol. 2, pp 37-68;
3. (c)Sawamoto, M.; Kanaoka, S.; Higashimura, T. In HyperStructured Molecules I: Chemistry, Physics and Application; Sasabe, H., Ed.; Gordon & Breach: Amsterdam, 1999; pp 43-61.
4. Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Macromolecules 2001, 34, 215-221.
5. Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Macromolecules 2001, 34, 7629-7635.
6. Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. J Polym Sci Part A: Polym Chem 2002, 40, 633-641.
7. Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. J Polym Sci Part A: Polym Chem 2002, 40, 1972-1982.
8. Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. J Polym Sci Part A: Polym Chem 2002, 40, 2245-2255.
9. For recent reviews on living radical polymerization, see (a) Kamigaito, M.; Ando, T.; Sawamoto, M. Chem Rev 2001,101, 3689-3746;
10. (b) Matyjaszewski, K.; Xia, J. Chem Rev 2001, 101, 2921-2990;
11. (c)Hawker, C. J.; Bosma, A. W.; Harth, E. Chem Rev 2001, 101, 3661-3688;
12. (d)Matyjaszewski, K., Ed.; Controlled/Living Radical Polymerization; ACS Symposium Series 768; American Chemical Society: Washington, DC, 2000;
13. (e) Sawamoto, M.; Kamigaito, M. In Synthesis of Polymers; Schluter, A.-D., Ed.; Materials Science and Technology Series; Wiley-VCH: Weinheim, 1999; Chapter 6, pp 163-194.
14. Senoo, M.; Kotani, Y.; Kamigaito, M.; Sawamoto, M. Macromolecules 1999, 32, 8005-8009.
15. Kanaoka, S.; Sawamoto, M.; Higashimura, T. Macromolecules 1993, 26, 254-259.
16. Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Macromolecules 2002, 35, 1493-1498.
17. Matyjaszewski, K. Polym Int 2003, 52, 1559-1565.
18. Mori, H.; Muller, A. H. E. Prog Polym Sci 2003, 23, 1403-1439.
19. For reviews on dendrimer and dendrimer catalysts, see (a) Grayson, S.; Fréchet, J. M. J. Chem Rev 2001, 101, 3819-3868;
20. (b) Oosterom, G. E.; Reek, J. N. H.; Kamer, P. C. J.; van Leeuwen, P. M. N. M. Angew Chem Int Ed 2001, 40, 1828-1849;
21. (c)Astruc, D.; Chardac, F. Chem Rev 2001, 101, 2991-3024;
22. (d)Crooks, R. M.; Zhao, M.; Sun, L.; Chechik, V.; Yeung, A. D. Ace Chem Res 2001, 34, 181-190;
23. (e) Twyman, L. J.; King, A. S. H.; Martin, I. K. Chem Soc Rev 2002, 31, 69-82.
24. Mecking, S.; Thomann, R.; Frey, H.; Sunder, A. Macromolecules 2000, 33, 3958-3960.
25. Bosman, A. W.; Vestberg, R.; Heumann, A.; Fréchet, J. M. J.; Hawker, C. J. J Am Chem Soc 2003, 125, 715-728.
26. Slagt, M. Q.; Stiriba, S.-E.; Klein Gebbink, R. J. M.; Kautz, H.; Frey, H.; van Koten, G. Macromolecules 2002, 35, 5734-5737.
27. Terashima, T.; Kamigaito, M.; Baek, K.-Y.; Ando, T.; Sawamoto, M. J Am Chem Soc 2003, 125, 5288-5289.
28. Rabinowitz, R.; Marcus, R. J Org Chem 1961, 26, 4157-4158.
29. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721-1723.
30. Hamasaki, S.; Kamigaito, M.; Sawamoto, M. Macromolecules 2002, 35, 2934-2940.
31. Rabinowitz, R.; Marcus, R.; Pellon, J. J Polym Sci Part A: Gen Pap 1964, 2, 1241-1249.
32. Kotani, Y; Kamigaito, M.; Sawamoto, M. Macromolecules 1998, 31, 5582-5587.
33. Börner, H. G.; Beers, K.; Matyjaszewski, K.; Sheiko, S. S.; Möller, M. Macromolecules 2001, 34, 4375-4383.