Star-shaped polymers by metal-catalyzed living radical polymerization. 1. Design of Ru(II)-based systems and divinyl linking agents

Macromolecules

Volumn 34, Issue 2, 2001, Pages 215-221

  Baek, Kyung Youl ^a   Kamigaito, Masami ^a   Sawamoto, Mitsuo ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CHLORINE; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); RUTHENIUM COMPOUNDS;

LIVING POLYMERIZATION; STAR-SHAPED POLYMERS;

AROMATIC POLYMERS;

EID: 0034832320     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma000751l     Document Type: Article

References (34)

1. This work was presented in part at the following meetings: (a) The 46th Symposium on Macromolecules, the Society of Polymer Science, Nagoya, Japan, Oct 1997; paper 2B16: Baek, K.-Y.; Ueda, J.; Kotani, Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. Jpn. 1997,46 (8), 154. (b) The 47th Annual Meeting on the Society of Polymer Science, Kyoto, Japan, May 1998; paper II-3-25: Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. Jpn. 1998, 47 (2), 155. (c) The 218th National Meeting on the American Chemical Society, New Orleans, LA, Aug 1999: Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1999, 40 (2), 472.
2. This work was presented in part at the following meetings: (a) The 46th Symposium on Macromolecules, the Society of Polymer Science, Nagoya, Japan, Oct 1997; paper 2B16: Baek, K.-Y.; Ueda, J.; Kotani, Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. Jpn. 1997,46 (8), 154. (b) The 47th Annual Meeting on the Society of Polymer Science, Kyoto, Japan, May 1998; paper II-3-25: Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. Jpn. 1998, 47 (2), 155. (c) The 218th National Meeting on the American Chemical Society, New Orleans, LA, Aug 1999: Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1999, 40 (2), 472.
3. This work was presented in part at the following meetings: (a) The 46th Symposium on Macromolecules, the Society of Polymer Science, Nagoya, Japan, Oct 1997; paper 2B16: Baek, K.-Y.; Ueda, J.; Kotani, Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. Jpn. 1997,46 (8), 154. (b) The 47th Annual Meeting on the Society of Polymer Science, Kyoto, Japan, May 1998; paper II-3-25: Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. Jpn. 1998, 47 (2), 155. (c) The 218th National Meeting on the American Chemical Society, New Orleans, LA, Aug 1999: Baek, K.-Y.; Kamigaito, M.; Sawamoto, M. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1999, 40 (2), 472.
4. For reviews, see: (a) Bauer, B. J.; Fetters, L. J. Rubber Chem. Technol. 1978, 51, 406. (b) Bywater, S. Adv. Polym. Sci. 1979, 30, 90. (c) Marsalkó, T. M.; Majoros, I.; Kennedy, J. P. Pure Appl. Chem. 1997, A34, 775.
5. For reviews, see: (a) Bauer, B. J.; Fetters, L. J. Rubber Chem. Technol. 1978, 51, 406. (b) Bywater, S. Adv. Polym. Sci. 1979, 30, 90. (c) Marsalkó, T. M.; Majoros, I.; Kennedy, J. P. Pure Appl. Chem. 1997, A34, 775.
6. For reviews, see: (a) Bauer, B. J.; Fetters, L. J. Rubber Chem. Technol. 1978, 51, 406. (b) Bywater, S. Adv. Polym. Sci. 1979, 30, 90. (c) Marsalkó, T. M.; Majoros, I.; Kennedy, J. P. Pure Appl. Chem. 1997, A34, 775.
7. For reviews on synthesis of star-shaped polymers by ionic living polymerizations, see: (a) Morton, M. Anionic Polymerization: Principle and Practice; Academic Press: New York, 1983; pp 221-232. (b) Hsieh, H. L.; Quirk, R. P. Anionic Polymerization; Marcel Dekker: New York, 1996; pp 333- 368. (c) Simms, J. A.; Spinelli, H. J. In Macromolecular Design of Polymeric Materials; Hatada, K., Kitayama, T., Vogl, O., Eds.; Marcel Dekker: New York, 1997; pp 379- 391. (d) Sawamoto, M. In Cationic Polymerization; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; pp 412- 420. (e) Sawamoto, M.; Kamigaito, M. In New Methods of Polymer Synthesis; Ebdon, J. R., Eastmond, G. C., Eds.; Blackie: Glasgow, 1995; Vol. 2, pp 37-68.
8. For reviews on synthesis of star-shaped polymers by ionic living polymerizations, see: (a) Morton, M. Anionic Polymerization: Principle and Practice; Academic Press: New York, 1983; pp 221-232. (b) Hsieh, H. L.; Quirk, R. P. Anionic Polymerization; Marcel Dekker: New York, 1996; pp 333-368. (c) Simms, J. A.; Spinelli, H. J. In Macromolecular Design of Polymeric Materials; Hatada, K., Kitayama, T., Vogl, O., Eds.; Marcel Dekker: New York, 1997; pp 379- 391. (d) Sawamoto, M. In Cationic Polymerization; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; pp 412- 420. (e) Sawamoto, M.; Kamigaito, M. In New Methods of Polymer Synthesis; Ebdon, J. R., Eastmond, G. C., Eds.; Blackie: Glasgow, 1995; Vol. 2, pp 37-68.
9. For reviews on synthesis of star-shaped polymers by ionic living polymerizations, see: (a) Morton, M. Anionic Polymerization: Principle and Practice; Academic Press: New York, 1983; pp 221-232. (b) Hsieh, H. L.; Quirk, R. P. Anionic Polymerization; Marcel Dekker: New York, 1996; pp 333- 368. (c) Simms, J. A.; Spinelli, H. J. In Macromolecular Design of Polymeric Materials; Hatada, K., Kitayama, T., Vogl, O., Eds.; Marcel Dekker: New York, 1997; pp 379-391. (d) Sawamoto, M. In Cationic Polymerization; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; pp 412- 420. (e) Sawamoto, M.; Kamigaito, M. In New Methods of Polymer Synthesis; Ebdon, J. R., Eastmond, G. C., Eds.; Blackie: Glasgow, 1995; Vol. 2, pp 37-68.
10. For reviews on synthesis of star-shaped polymers by ionic living polymerizations, see: (a) Morton, M. Anionic Polymerization: Principle and Practice; Academic Press: New York, 1983; pp 221-232. (b) Hsieh, H. L.; Quirk, R. P. Anionic Polymerization; Marcel Dekker: New York, 1996; pp 333- 368. (c) Simms, J. A.; Spinelli, H. J. In Macromolecular Design of Polymeric Materials; Hatada, K., Kitayama, T., Vogl, O., Eds.; Marcel Dekker: New York, 1997; pp 379- 391. (d) Sawamoto, M. In Cationic Polymerization; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; pp 412-420. (e) Sawamoto, M.; Kamigaito, M. In New Methods of Polymer Synthesis; Ebdon, J. R., Eastmond, G. C., Eds.; Blackie: Glasgow, 1995; Vol. 2, pp 37-68.
11. For reviews on synthesis of star-shaped polymers by ionic living polymerizations, see: (a) Morton, M. Anionic Polymerization: Principle and Practice; Academic Press: New York, 1983; pp 221-232. (b) Hsieh, H. L.; Quirk, R. P. Anionic Polymerization; Marcel Dekker: New York, 1996; pp 333- 368. (c) Simms, J. A.; Spinelli, H. J. In Macromolecular Design of Polymeric Materials; Hatada, K., Kitayama, T., Vogl, O., Eds.; Marcel Dekker: New York, 1997; pp 379- 391. (d) Sawamoto, M. In Cationic Polymerization; Matyjaszewski, K., Ed.; Marcel Dekker: New York, 1996; pp 412- 420. (e) Sawamoto, M.; Kamigaito, M. In New Methods of Polymer Synthesis; Ebdon, J. R., Eastmond, G. C., Eds.; Blackie: Glasgow, 1995; Vol. 2, pp 37-68.
12. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
13. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
14. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
15. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
16. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
17. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
18. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH-Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
19. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
20. For recent reviews on living radical polymerization, see: (a) Georges, M. K.; Vergin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 356. (c) Hawker, C. J. Trends Polym. Sci. 1996, 4, 183. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Hawker, C. J. Acc. Chem. Res. 1997, 30, 373. (g) Sawamoto, M.; Kamigaito, M. Polymer Synthesis (Materials Science and Technology Series); Schülter, A.-D., Ed.; VCH- Wiley: Weinheim, Germany, 1999; Chapter 6. (h) Sawamoto, M.; Kamigaito, M. CHEMTECH 1999, 29 (6), 30. (i) Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
21. Ueda, J.; Matsuyama, M.; Kamigaito, M.; Sawamoto, M. Macromolecules 1998, 31, 557.
22. Ueda, J.; Kamigaito, M.; Sawamoto, M. Macromolecules 1998, 31. 6762.
23. Angot, S.; Murthy, K. S.; Taton, D.; Gnanou, Y. Macromolecules 1998, 31, 7218.
24. Matyjaszewski, K.; Miller, P. J.; Pyun, J.; Kickelbick, G.; Diamanti, S. Macromolecules 1999, 32, 6526.
25. Xia, J.; Zhang, X.; Matyjaszewski, K. Macromolecules 1999, 32, 4482.
26. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 25, 1721.
27. Ando, T.; Kato, M.; Kamigaito, M.; Sawamoto, M. Macromolecules 1996, 29, 1070.
28. Ando, T.; Kamigaito, M.; Sawamoto, M. Macromolecules 1998, 31, 6708.
29. Ando, T.; Kamigaito, M.; Sawamoto, M. Tetrahedron 1997, 53, 15445.
30. Ando, T.; Kamigaito, M.; Sawamoto, M. Macromolecules 1997, 30, 4507.
31. Takahashi, H.; Ando, T.; Kamigaito, M.; Sawamoto, M. Macromolecules 1999, 32, 3820.
32. Kanaoka, S.; Sawamoto, M.; Higashimura, T. Macromolecules 1991, 24, 2309.
33. Hiroji, F.; Sawamoto, M.; Higashimura, T. Macromolecules 1993, 26, 7315.
34. z(gyration radius) = 11.3 nm, and f = 29].