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Volumn 128, Issue 35, 2006, Pages 11679-11692

On the reactivity of surface methoxy species in acidic zeolites

Author keywords

[No Author keywords available]

Indexed keywords

ACIDITY; CARBONYLATION; CATALYST ACTIVITY; ETHERS; METHANE; NUCLEAR MAGNETIC RESONANCE; POSITIVE IONS; THERMAL EFFECTS;

EID: 33748368269     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja061018y     Document Type: Article
Times cited : (168)

References (106)
  • 24
    • 0000500837 scopus 로고
    • The reactivity theory of Brønsted Acid Sites was discussed in: (e) van Santen, R. A. Chem. Rev. 1995, 95, 637-660.
    • (1995) Chem. Rev. , vol.95 , pp. 637-660
    • Van Santen, R.A.1
  • 57
    • 33748347094 scopus 로고    scopus 로고
    • Catalysts for Manufacturing Methyl Chloride. Japanese Patent 58-27644, 1983
    • Magoren. Catalysts for Manufacturing Methyl Chloride. Japanese Patent 58-27644, 1983.
    • Magoren1
  • 75
    • 0025229275 scopus 로고
    • The effect of oxygen cofeeding on the conversion of methanol or dimethyl ether on acidic zeolites was discussed in: (b) Hutchings, G. J.; Hunter, R. Catal. Today 1990, 6, 279-306.
    • (1990) Catal. Today , vol.6 , pp. 279-306
    • Hutchings, G.J.1    Hunter, R.2
  • 98
    • 0001859236 scopus 로고
    • For discussion of the Hammond Postulate, for example, see: Farcasiu, D. J. Chem. Educ. 1975, 52, 76-79.
    • (1975) Chem. Educ. , vol.52 , pp. 76-79
    • Farcasiu, D.J.1
  • 100
    • 0002354275 scopus 로고
    • 13C MAS NMR signal of methane (at ca. -9 ppm) was observed in Figure 6d and 6e upon thermal treatments at 573 and 673 K, respectively. Therefore, the latter possibility cannot be absolutely ruled out, although methane formation is hardly observed at 493 and 523 K (see Figure 6b and 6c).
    • (1991) Chem. Rev. , vol.91 , pp. 335-362
    • Bunnelle, W.H.1
  • 104
    • 0004749751 scopus 로고
    • For experimental evidence of the C-H bond activation upon decomposition of surface methoxy species, for example, see the references listed in Table 1. Some of additional evidence was presented in: (a) Novakova, J.; Kubelkova, L.; Dolejsek, Z. J. Catal. 1986, 97, 277-279.
    • (1986) J. Catal. , vol.97 , pp. 277-279
    • Novakova, J.1    Kubelkova, L.2    Dolejsek, Z.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.