Interaction of olefins with carbon monoxide on zeolite H-ZSM-5. NMR observation of the Friedel-Crafts acylation of alkenes at ambient temperature

Journal of the American Chemical Society

Volumn 118, Issue 44, 1996, Pages 10890-10891

  Luzgin, Mikhail V ^a   Romannikov, Vyacheslav N ^a   Stepanov, Alexander G ^a   Zamaraev, Kirill I ^a  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

KETONE;

ARTICLE; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS;

EID: 0029840851     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9615381     Document Type: Article

References (35)

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27. Conclusions on the existence of alkyl carbenium ions in zeolites as transient intermediates with vanishing steady-state concentration have been reported on the basis of NMR data: (a) Aronson, M. T.; Gorte, R. J.; Farneth, W. E.; While, D. J. Am. Chem. Soc. 1989, 111, 840-846. (b) Lazo, N. D.; Richardson, B. R.; Schettler, P. D.; White, J. L.; Munson, E. J.; Haw, J. F. J. Phys. Chem. 1991, 95, 9420-9425. (c) Stepanov, A. G.; Zamaraev, K. I.; Thomas, J. M. Catal. Lett. 1992, 13. 407-422. (d) Xu, T.; Haw, J. F. J. Am. Chem. Soc. 1994, 116, 7753-7759. (e) Stepanov, A. G. Catal. Today 1995, 24, 341-348 and refs 16, 17, and 24 of this paper.
28. Conclusions on the existence of alkyl carbenium ions in zeolites as transient intermediates with vanishing steady-state concentration have been reported on the basis of NMR data: (a) Aronson, M. T.; Gorte, R. J.; Farneth, W. E.; While, D. J. Am. Chem. Soc. 1989, 111, 840-846. (b) Lazo, N. D.; Richardson, B. R.; Schettler, P. D.; White, J. L.; Munson, E. J.; Haw, J. F. J. Phys. Chem. 1991, 95, 9420-9425. (c) Stepanov, A. G.; Zamaraev, K. I.; Thomas, J. M. Catal. Lett. 1992, 13. 407-422. (d) Xu, T.; Haw, J. F. J. Am. Chem. Soc. 1994, 116, 7753-7759. (e) Stepanov, A. G. Catal. Today 1995, 24, 341-348 and refs 16, 17, and 24 of this paper.
29. Conclusions on the existence of alkyl carbenium ions in zeolites as transient intermediates with vanishing steady-state concentration have been reported on the basis of NMR data: (a) Aronson, M. T.; Gorte, R. J.; Farneth, W. E.; While, D. J. Am. Chem. Soc. 1989, 111, 840-846. (b) Lazo, N. D.; Richardson, B. R.; Schettler, P. D.; White, J. L.; Munson, E. J.; Haw, J. F. J. Phys. Chem. 1991, 95, 9420-9425. (c) Stepanov, A. G.; Zamaraev, K. I.; Thomas, J. M. Catal. Lett. 1992, 13. 407-422. (d) Xu, T.; Haw, J. F. J. Am. Chem. Soc. 1994, 116, 7753-7759. (e) Stepanov, A. G. Catal. Today 1995, 24, 341-348 and refs 16, 17, and 24 of this paper.
30. Conclusions on the existence of alkyl carbenium ions in zeolites as transient intermediates with vanishing steady-state concentration have been reported on the basis of NMR data: (a) Aronson, M. T.; Gorte, R. J.; Farneth, W. E.; While, D. J. Am. Chem. Soc. 1989, 111, 840-846. (b) Lazo, N. D.; Richardson, B. R.; Schettler, P. D.; White, J. L.; Munson, E. J.; Haw, J. F. J. Phys. Chem. 1991, 95, 9420-9425. (c) Stepanov, A. G.; Zamaraev, K. I.; Thomas, J. M. Catal. Lett. 1992, 13. 407-422. (d) Xu, T.; Haw, J. F. J. Am. Chem. Soc. 1994, 116, 7753-7759. (e) Stepanov, A. G. Catal. Today 1995, 24, 341-348 and refs 16, 17, and 24 of this paper.
31. Conclusions on the existence of alkyl carbenium ions in zeolites as transient intermediates with vanishing steady-state concentration have been reported on the basis of NMR data: (a) Aronson, M. T.; Gorte, R. J.; Farneth, W. E.; While, D. J. Am. Chem. Soc. 1989, 111, 840-846. (b) Lazo, N. D.; Richardson, B. R.; Schettler, P. D.; White, J. L.; Munson, E. J.; Haw, J. F. J. Phys. Chem. 1991, 95, 9420-9425. (c) Stepanov, A. G.; Zamaraev, K. I.; Thomas, J. M. Catal. Lett. 1992, 13. 407-422. (d) Xu, T.; Haw, J. F. J. Am. Chem. Soc. 1994, 116, 7753-7759. (e) Stepanov, A. G. Catal. Today 1995, 24, 341-348 and refs 16, 17, and 24 of this paper.
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33. The signals from C-α and C-β carbon atoms in small conjugated α,β-unsaturated ketones (e.g., mesityl oxide) adsorbed on H-ZSM-5 are observed at 122 and 188-190 ppm, respectively, see refs 10 and 11.
34. Stepanov, A. G.; Luzgin, M. V.; Romannikov, V. N.; Zamaraev, K. I. Catal. Lett. 1994, 24, 271-284.
35. Evans, D. A.; Nelson, J. V.; Vogel, E.; Taber. T. R. J. Am. Chem. Soc. 1981, 103, 3099-3111.