Effects of substituents in cyclopentadienyltitanium trichlorides on electronic absorption and 47,49Ti NMR spectra and styrene polymerization activated by methylalumoxane

Journal of Molecular Catalysis A: Chemical

Volumn 257, Issue 1-2, 2006, Pages 14-25

  Pinkas, Jiří ^a   Lyčka, Antonín ^b   Šindelář, Pavel ^c   Gyepes, Róbert ^d   Varga, Vojtech ^e   Kubišta, Jiří ^a   Horáček, Michal ^a   Mach, Karel ^a  

^a J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^b Vyzkumny ustav organickych syntez as   (Czech Republic)

^c Polymer Institute Brno   (Czech Republic)

^d CHARLES UNIVERSITY   (Czech Republic)

^e RESEARCH INSTITUTE OF INORGANIC CHEMISTRY   (Czech Republic)

Author keywords

47Ti and 49Ti NMR; Electronic absorption spectra; Half sandwich titanocenes; Styrene polymerization; Substituent effects; Syndiotactic polystyrene; Titanium

Indexed keywords

CATALYST ACTIVITY; ELECTROMAGNETIC WAVE ABSORPTION; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; SPECTRUM ANALYSIS; STYRENE;

47TI AND 49TI NMR; ELECTRONIC ABSORPTION SPECTRA; HALF-SANDWICH TITANOCENES; STYRENE POLYMERIZATION; SUBSTITUENT EFFECTS; SYNDIOTACTIC POLYSTYRENE;

TITANIUM COMPOUNDS;

EID: 33748289467     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2006.05.016     Document Type: Article

References (58)

1. Brintzinger H.-H., Fischer D., Mülhaupt R., Rieger B., and Waymouth R.M. Angew. Chem., Int. Ed. Engl. 34 (1995) 1143
2. Möhring P.C., and Coville N.J. J. Organomet. Chem. 479 (1994) 1
3. Bochmann M. J. Chem. Soc. Dalton Trans. (1996) 255
4. Gassman P.G., Macomber D.W., and Hershberger J.W. Organometallics 2 (1983) 1470
5. Vondrák T., Mach K., and Varga V. J. Organomet. Chem. 367 (1989) 69
6. Vondrák T., Mach K., and Varga V. Organometallics 11 (1992) 2030
7. Kidd R.G., Mathews R.W., and Spinney H.G. J. Am. Chem. Soc. 94 (1972) 6686
8. Hao N., Sayer B.G., Denes G., Bickley D.G., and McGlinchey M.J. J. Magn. Reson. 50 (1982) 50
9. Dormond A., Fauconet M., Leblanc J.C., and Moise C. Polyhedron 3 (1984) 897
10. Gassman P.G., Campbell P.H., and Macomber D.W. Organometallics 3 (1984) 385
11. Finch W.C., Anslyn E.V., and Grubbs R.H. J. Am. Chem. Soc. 110 (1988) 2406
12. Sarsfield M.J., Ewart S.W., Tremblay T.L., Roszak A.W., and Baird M.C. J. Chem. Soc., Faraday Trans. (1997) 3097
13. Hafner A., Duthaler R.O., Marti R., Rihs G., Rothe-Streit P., and Schwarzenbach F. J. Am. Chem. Soc. 114 (1992) 2321
14. Berger S., Bock W., Marth C.F., Raguse B., and Reetz M.T. Magn. Reson. Chem. 28 (1990) 559
15. Benn R., and Rufińska A. J. Organomet. Chem. 273 (1984) C51
16. Siedle A.R., Newmark R.A., Gleason W.B., and Lamanna W.M. Organometallics 9 (1990) 1290
17. Bühl M., Hopp G., von Philipsborn W., Beck S., Prosenc M.H., Rief U., and Brintzinger H.H. Organometallics 15 (1996) 778
18. Langmaier J., Samec Z., Varga V., Horáček M., and Mach K. J. Organomet. Chem. 579 (1999) 348
19. Mach K., and Raynor J.B. J. Chem. Soc. Dalton Trans. (1992) 683
20. Hiller J., Thewalt U., Polášek M., Petrusová L., Varga V., Sedmera P., and Mach K. Organometallics 15 (1996) 3752
21. Mach K., Varga V., Antropiusová H., and Poláček J. J. Organomet. Chem. 333 (1987) 205
22. Hafner A., and Okuda J. Organometallics 12 (1993) 949
23. Erben M., Růžička A., Picka M., and Pavlík I. Magn. Reson. Chem. 42 (2004) 414
24. Skeřil R., Šindelář P., Salajka Z., Varga V., Císařová I., Pinkas J., Horáček M., and Mach K. J. Mol. Catal. A 224 (2004) 97
25. Staal O.K.B., Beetstra D.J., Jekel A.P., Hessen B., Teuben J.H., Štěpnička P., Gyepes R., Horáček M., Pinkas J., and Mach K. Collect. Czech. Chem. Commun. 68 (2003) 1119
26. Ishihara N., Seimiya T., Kuramoto M., and Uoi M. Macromolecules 19 (1986) 2464
27. Ishihara N., Kuramoto M., and Uoi M. Macromolecules 21 (1988) 3356
28. Tomotsu N., Ishihara N., Newman T.H., and Malanga M.T. J. Mol. Catal. A 128 (1998) 167
29. Yokota K., Inoue T., Naganuma S., Shozaki H., Tomotsu N., Kuramoto M., and Ishihara N. In: Kaminski W. (Ed). Metaloorganic Catalysts for Synthesis and Polymerization (1999), Springer, Berlin 435
30. Schellenberg J., and Tomotsu N. Prog. Polym. Sci. 27 (2002) 1925
31. Qian Y., Huang J., Bala M.D., Lian B., Zhang H., and Zhang H. Chem. Rev. 103 (2003) 2633
32. Longo P., Proto A., and Zambelli A. Macromol. Chem. Phys. 196 (1995) 3015
33. Xu G., and Ruckenstein E. J. Polym. Sci., Part A: Polym. Chem. 37 (1999) 2481
34. Kaminsky W., Lenk S., Scholz V., Roesky H.W., and Herzog A. Macromolecules 30 (1997) 7647
35. Zemánek J., Fröhlichová L., Šindelář P., Štěpnička P., Císařová I., Varga V., Horáček M., and Mach K. Collect. Czech. Chem. Commun. 66 (2001) 1359
36. Lukešová L., Gyepes R., Pinkas J., Horáček M., Kubišta J., Čejka J., and Mach K. Collect. Czech. Chem. Commun. 70 (2005) 1589
37. Gorsich R.D. J. Am. Chem. Soc. 82 (1960) 4211
38. Llinas G.H., Mena M., Palacios F., Royo P., and Serrano R. J. Organomet. Chem. 340 (1988) 37
39. Terpstra A., Louwen J.N., Oskam A., and Teuben J.H. J. Organomet. Chem. 260 (1984) 207
40. Mason J. Polyhedron 8 (1989) 1657
41. Dechter J.J. Prog. Inorg. Chem. 33 (1985) 393
42. Kim Y., Koo B.H., and Do Y. J. Organomet. Chem. 527 (1997) 155
43. Gaussian 98, Revision A.7. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, V.G. Zakrzewski, J.A. Montgomery, Jr., R.E. Stratmann, J.C. Burant, S. Dapprich, J.M. Millam, A.D. Daniels, K.N. Kudin, M.C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G.A. Petersson, P.Y. Ayala, Q. Cui, K. Morokuma, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J. Cioslowski, J.V. Ortiz, A.G. Baboul, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, J.L. Andres, C. Gonzalez, M. Head-Gordon, E.S. Replogle, J.A. Pople, Gaussian, Inc., Pittsburgh, PA, 1998.
44. Engelhardt L.M., Papasergio R.I., Raston C.L., and White A.H. Organometallics 3 (1984) 18
45. Evans W.J., Giarikos D.G., and Ziller J.W. J. Organomet. Chem. 688 (2003) 200
46. Alcock N.W., Toogood G.E., and Wallbridge M.G.H. Acta Crystallogr., Sec.C 40 (1984) 598
47. Chien J.C.W., Salajka Z., and Dong S. Macromolecules 25 (1992) 3199
48. Xu G., and Lin S. Macromolecules 30 (1997) 685
49. Ready T.E., Gurge R., Chien J.C.W., and Rausch M.D. Organometallics 17 (1998) 5236
50. Grassi A., Lamberti C., Zambelli A., and Mingozzi I. Macromolecules 30 (1997) 1884
51. Williams E.F., Murray M.C., and Baird M.C. Macromolecules 33 (2000) 261
52. Antropiusová H., Dosedlová A., Hanuš V., and Mach K. Transit. Met. Chem. (London) 6 (1981) 90
53. Horáček M., Gyepes R., Císařová I., Polášek M., Varga V., and Mach K. Collect. Czech. Chem. Commun. 61 (1996) 1307
54. Lukešová L., Horáček M., Gyepes R., Císařová I., Štěpnička P., Kubišta J., and Mach K. Collect. Czech. Chem. Commun. 70 (2005) 11
55. Pinkas J., Kubišta J., Gyepes R., Císařová I., Pirio N., Meunier Ph., and Mach K. J. Organomet. Chem. 690 (2005) 731
56. Zemánek J., Štěpnička P., Fejfarová K., Gyepes R., Císařová I., Horáček M., Kubišta J., Varga V., and Mach K. Collect. Czech. Chem. Commun. 66 (2001) 605
57. Altomare A., Burla M.C., Camalli M., Cascarano G., Giacovazzo C., Guagliardi A., and Polidori G. J. Appl. Crystallogr. 27 (1994) 435
58. Sheldrick G.M. SHELXL-97. Program for Crystal Structure Refinement from Diffraction Data (1997), University of Göttingen, Göttingen