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Volumn 125, Issue 7, 2006, Pages

Fragility and thermodynamics in nonpolymeric glass-forming liquids

Author keywords

[No Author keywords available]

Indexed keywords

FRAGILITY; HYPERBOLIC FUNCTIONS; NONPOLYMERIC GLASS FORMING LIQUIDS; SUPERCOOLED LIQUIDS;

EID: 33747758436     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2244551     Document Type: Article
Times cited : (302)

References (155)
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    • edited by K. L. Ngai and G. B. Wright (National Technical Information Service, U. S. Department of Commerce, Springfield, VA)
    • C. A. Angell, in Relaxations in Complex Systems, edited by K. L. Ngai and G. B. Wright (National Technical Information Service, U. S. Department of Commerce, Springfield, VA, 1985).
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    • C. Hansen, F. Stickel, R. Richert, and E. W. Fischer, J. Chem. Phys. 108, 6408 (1998), where fragilities of n-propylbenzene and n-butylbenzene are 69 and 67, respectively. Dielectric relaxation measurements show that the fragility of ethylbenzene is 58 (see Ref. 115).
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    • Hansen, C.1    Stickel, F.2    Richert, R.3    Fischer, E.W.4
  • 41
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    • (1995)
    • Fan, J.1
  • 84
    • 33747796215 scopus 로고
    • Ph.D. thesis, Arizona State University
    • E. M. Sanchez-Cervantes, Ph.D. thesis, Arizona State University (1994).
    • (1994)
    • Sanchez-Cervantes, E.M.1
  • 97
    • 31644444390 scopus 로고    scopus 로고
    • g = T(100 s) = 182 K. This value is close to m = 67 at τ = 100 s when using the data from G. Power, J. K. Vij, and G. P. Johari, J. Chem. Phys. 124, 044513 (2006).
    • (2006) J. Chem. Phys. , vol.124 , pp. 044513
    • Power, G.1    Vij, J.K.2    Johari, G.P.3
  • 106
    • 23044481877 scopus 로고    scopus 로고
    • m = 98 of m-toludine is from the combination of various measurements shown in A. Mandanici, M. Cutroni, and R. Richert, J. Chem. Phys. 122, 084508 (2005).
    • (2005) J. Chem. Phys. , vol.122 , pp. 084508
    • Mandanici, A.1    Cutroni, M.2    Richert, R.3
  • 115
    • 0028498708 scopus 로고
    • This fragility value is in good agreement with m ∼ 90 from the low-temperature viscosity data: D. J. Plazek, C. A. Bero, and I.-C. Chang, J. Non-Cryst. Solids 172-174, 181 (1994).
    • (1994) J. Non-cryst. Solids , vol.172-174 , pp. 181
    • Plazek, D.J.1    Bero, C.A.2    Chang, I.-C.3
  • 120
    • 33747762203 scopus 로고
    • Ph.D. thesis, Purdue University
    • 2O (n = 1-4) systems exhibit fragility changing from 52 to 70. m = 95 is reported in Ref. 10, but this result is not reliable since it involves extrapolation from high-temperature viscosity data.
    • (1971)
    • Sare, E.J.1
  • 126
    • 33747779287 scopus 로고    scopus 로고
    • L.-M. Wang and C. A. Angell (unpublished)
    • g=184 K) [L.-M. Wang and C. A. Angell (unpublished)] by using the calorimetry method as described in Ref. 12. This high kinetic fragility is also in agreement with the fragile thermodynamic counterpart shown in Refs. 58 and 5.
  • 133
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    • 3 at glass transition are quite divergent. Other references are S. B. Thomas and G. S. Parks, J. Phys. Chem. 35, 2091 (1931);
    • (1931) J. Phys. Chem. , vol.35 , pp. 2091
    • Thomas, S.B.1    Parks, G.S.2
  • 140
    • 26444464974 scopus 로고
    • S. S. N. Murthy and S. K. Nayak, J. Chem. Phys. 99, 5362 (1993). The fragility value is based on the true α process, not on the Debye relaxation.
    • (1993) J. Chem. Phys. , vol.99 , pp. 5362
    • Murthy, S.S.N.1    Nayak, S.K.2
  • 144
    • 33747795533 scopus 로고    scopus 로고
    • A. Mandanici and R. Richert (unpublished)
    • m = 58 of ethylbenzene is from dielectric relaxation. A. Mandanici and R. Richert (unpublished).
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    • 0000332325 scopus 로고
    • 13 Ps. The value changes by <10% when combining the viscosity with the high-temperture data from A. J. Barlow, J. Lamb, and A. J. Matheson, Proc. R. Soc. London, Ser. A 292, 322 (1966). (Note that an ∼2 K temperature shift is needed to match the two sets of data).
    • (1966) Proc. R. Soc. London, Ser. A , vol.292 , pp. 322
    • Barlow, A.J.1    Lamb, J.2    Matheson, A.J.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.