Direct determination of kinetic fragility indices of glassforming liquids by differential scanning calorimetry: Kinetic versus thermodynamic fragilities

Journal of Chemical Physics

Volumn 117, Issue 22, 2002, Pages 10184-10192

  Wang, Li Min ^a   Velikov, V ^a   Angell, C A ^a  

^a ARIZONA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIELECTRIC RELAXATION; DIFFERENTIAL SCANNING CALORIMETRY; ENTHALPY; ENTROPY; GLASS; GLASS TRANSITION; QUENCHING; REACTION KINETICS; SPECIFIC HEAT; SPECTROSCOPIC ANALYSIS; THERMAL EFFECTS; VISCOSITY;

GLASSFORMING LIQUIDS; HEAT CAPACITY SPECTROSCOPY; KINETIC FRAGILITY INDICES;

LIQUIDS;

EID: 0037045179     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1517607     Document Type: Article

References (88)

1. C. A. Angell, in Relaxation in Complex Systems, edited by K. L. Ngai and G. B. Wright (NRL, Washington, DC, 1985).
2. M. Tatsumisago, B. L. Halfpap, J. L. Green, S. M. Lindsay, and C. A. Angell, Phys. Rev. Lett. 64, 1549 (1990).
3. R. B̈homer and C. A. Angell, Phys. Rev. B 45, 10091 (1992).
4. D. J. Plazek and K. L. Ngai, Macromolecules 24, 1222 (1991).
5. K. Ito, C. T. Moynihan, and C. A. Angell, Nature (London) 398, 492 (1999).
6. S. Sastry, Nature (London) 409, 164 (2001).
7. R. Richert and C. A. Angell, J. Chem. Phys. 108, 9016 (1998).
8. H. Vogel, Phys. Z. 22, 645 (1921)
9. G. S. Fulcher, J. Am. Chem. Soc. 8, 339 (1923)
10. G. Tammann and W. Z. Hesse, Anorg. Allgem. Chem. 156, 245 (1926).
11. C. Hansen, F. Stickel, T. Berger, R. Richert, and E. W. Fischer, J. Chem. Phys. 107, 1086 (1997).
12. W. Gotze and L. Sjogren, Rep. Prog. Phys. 55, 241 (1992).
13. F. Stickel, E. W. Fischer, and R. Richert, J. Chem. Phys. 102, 6251 (1995)
14. F. Stickel, E. W. Fischer, and R. Richert, J. Chem. Phys. 104, 2043 (1996).
15. E. Rössler and A. P. Sokolov, Chem. Geol. 128, 143 (1996).
16. C. A. Angell, J. Phys. Chem. Solids 49, 863 (1988)
17. C. A. Angell, Science 267, 1924 (1995).
18. J. L. Barrat and M. L. Klein, Ann. Rev. Phys. Chem. 42, 23 (1991).
19. A. Sokolov, Endeavor 21, 109 (1997).
20. C. A. Angell, J. Res. Natl. Inst. Stand. Technol. 102, 171 (1997).
21. L.-M. Martinez and C. A. Angell, Nature (London) 410, 663 (2001).
22. F. H. Stillinger and P. G. Debenedetti, J. Chem. Phys. 116, 3353 (2002).
23. E. Rössler, K.-U. Hess, and V. Novikov, J. Non-Cryst. Solids 223, 207 (1998).
24. U. Buchenau, Phys. Rev. B 63, 104203 (2001).
25. K. J. Rao, S. Kumar, and M. H. Bhat, J. Phys. Chem. B 105, 9023 (2001).
26. X. L. Zhao and D. Kivelson, J. Phys. Chem. 99, 6721 (1995).
27. C. A. Angell and C. T. Moynihan, Metall. Mater. Trans. B 31, 4587 (2000)
28. C. T. Moynihan and C. A. Angell, J. Non-Cryst. Solids 274, 131 (2000)
29. C. A. Angell, J. Phys.: Condens. Matter 12, 6463 (2000).
30. T. A. Vilgis, Phys. Rev. B 47, 2882 (1993)
31. T. A. Vilgis, Phys. Rep. 336, 167 (2000).
32. R. Böhmer, K. L. Ngai, C. A. Angell, and D. J. Plazek, J. Chem. Phys. 99, 4201 (1993)
33. R. Böhmer and C. A. Angell, in Disorder Effects on Relaxational Processes, edited by A. Blumen and R. Richert (Springer, Berlin, 1994), p. 11.
34. J. L. Green, K. Ito, K. Xu, and C. A. Angell, J. Phys. Chem. B 103, 3991 (1999).
35. T. Moynihan, A. J. Easteal, M. A. DeBolt, and J. Tucker, J. Am. Chem. Soc. 59, 12 (1976)
36. M. A. DeBolt, A. J. Easteal, J. Wilder, and J. Tucker, J. Phys. Chem. 78, 2673 (1974)
37. K. J. Crowley and G. Zografi, Thermochim. Acta 380, 79 (2001).
38. J. L. Yarger, private communication.
39. I. M. Hodge, J. Non-Cryst. Solids 169, 211 (1994).
40. V. Velikov, S. Borick, and C. A. Angell, Science 294, 2335 (2001)
41. V. Velikov, S. Borick, and C. A. Angell, J. Phys. Chem. B 106, 1069 (2002).
42. G. M. Bartenev, Dokl. Akad. Nauk SSSR 76, 227 (1951).
43. I. Gutzow and J. Schmelzer, The Vitreous States (Springer, Berlin, 1995).
44. P. G. Debenedetti, Metastable liquids: concepts and principles (Princeton University Press, Princeton, N.J., 1996).
45. K. Vollmayr, W. Kob, and K. Binder, Phys. Rev. B 54, 15808 (1996).
46. C. T. Moynihan, J. Am. Chem. Soc. 59, 16 (1976).
47. C. T. Moynihan, in Assignment of the Glass Transition, ASTM STP 1249, edited by R. J. Seyler (American Society for Testing and Materials, Philadelphia, 1994).
48. Y. Z. Yue, J. deC. Christiansen, and S. L. Jensen, Chem. Phys. Lett. 357, 20 (2002).
49. K. Lantzky, D. Roddick, and J. L. Yarger (unpublished).
50. W. Suchanski, S. Jurga, T. Pakula, M. Paluch, and J. Ziolo, J. Phys. Condens. Matter 12, 9551 (2000).
51. B. Schiener, A. Loidl, R. V. Chamberlin, and R. Böhmer, J. Mol. Liq. 69, 243 (1996).
52. Calorimetric studies using the present method (Ref. 39) yield a value close to the value 126 extracted from the VET equation fits to the viscosity data of Ref. 43. A slightly lower number, 115, may be assessed from the di-electric data of Rössler and co-workers that extend down to Tg [S. Dvinskikh, G. Benini, J. Senker, M. Vogel, J. Wiedersich, A. Kudlik, and E. Rössler, J. Phys. Chem. B 103, 1727 (1999). See their Fig. 15.].
53. P. J. Chappell and D. Kivelson, J. Chem. Phys. 76, 1742 (1982).
54. C. Alba, L. E. Busse, D. J. List, and C. A. Angell, J. Chem. Phys. 92, 617 (1990).
55. The relaxation time data for decalin are from current work by K. Duvvuri and R. Richert, J. Chem. Phys. 117, 4414 (2002) (dieletric relaxation studies)
56. M. Yang and R. Richert, Chem. Phys. 284, 103 (2002) (solvation dynamics studies).
57. N. O. Birge, Phys. Rev. B 34, 1631 (1986).
58. P. Lunkenheimer, U. R. Brand, and A. Loidl, Contemp. Phys. 41, 15 (2002).
59. P. K. Dixon and S. R. Nagel, Phys. Rev. Lett. 61, 341 (1988)
60. P. K. Dixon, L. Wu, and S. R. Nagel, ibid. 65, 1108 (1990).
61. N. Menon and S. R. Nagel, Phys. Rev. Lett. 73, 963 (1994).
62. J. R. Huck, G. A. Noyel, L. J. Jorat, and A. M. Bondeau, J. Electrost. 12, 221 (1982).
63. S. W. Martin and C. A. Angell, J. Phys. Chem. 90, 6736 (1986).
64. D. H. Huang and G. B. McKenna, J. Chem. Phys. 114, 5621 (2001).
65. S. Sastry, Nature (London) 409, 164 (2001).
66. J. P. McCullough, H. L. Finke, J. F. Messerly, S. S. Todd, T. C. Kincheloe and G. Waddington, J. Chem. Phys. 61, 1105 (1997).
67. F. H. Stillinger and T. A. Weber, Science 228, 983 (1984).
68. E. La Nave, A. Scala, F. W. Starr, H. E. Stanley, and F. Sciortino, Phys. Rev. E 64, 036102 (2001).
69. D. Thorn Leeson and D. A. Wiersma, Phys. Rev. Lett. 74, 2138 (1995).
70. D. J. Wales, Science 293, 2067 (2002)
71. D. J. Wales, work presented at the second workshop on Unifying Concepts in Glass Physics (Rome, 2002).
72. C. T. Moynihan, V. Velikov, and C. A. Angell (unpublished work).
73. B. Wunderlich, J. Phys. Chem. 64, 1052 (1960).
74. A. Weitz and B. Wunderlich, J. Polym. Sci., Polym. Phys. Ed. 12, 2473 (1974).
75. N. J. Andrews and A. R. Ubbelohde, Proc. R. Soc. A 228, 435 (1955)
76. E. McLaughlin and A. R. Ubbelohde, Trans. Far. Soc. 54, 1804 (1958).
77. D. J. Plazek and J. H. Magill, J. Chem. Phys. 45, 3038 (1996).
78. P. K. Dixon et al., Phys. Rev. Lett. 61, 341 (1988)
79. H. Z. Cummins, W. M. Du, M. Fuchs, W. Götze, S. Hildebrand, A. Latz, G. Li, and N. J. Tao, Phys. Rev. E 47, 4223 (1993)
80. C. Glorieux, K. A. Nelson, G. Hinze, and M. D. Fayer, J. Chem. Phys. 116, 3384 (2002).
81. S. Sastry, P. G. Debenedetti, and F. H. Stillinger, Nature (London) 393, 554 (1998).
82. I. Cohen, A. Ha, X.-L. Zhao, M. Lee, T. Fisher, M. J. Strouse, and D. Kivelson, J. Phys. Chem. B 100, 8581 (1996)
83. M. L. Ferrer, H. Sakai, D. Kivelson, and C. Alba-Simionesco, ibid. 103, 4191 (1999).
84. E. Rössler, J. Chem. Phys. 92, 3725 (1990).
85. D. D. Brace, S. D. Gottke, H. Cang, and M. D. Fayer, J. Chem. Phys. 116, 1598 (2002).
86. W. Kob, F. Sciortino, and P. Tartaglia, Europhys. Lett. 49, 590 (2000).
87. I. Saika-Voivod, P. H. Poole, and F. Sciortino, Nature (London) 412, 514 (2001).
88. F. Sciortino, W. Kob, and P. Tartaglia, Phys. Rev. Lett. 83, 3214 (1999).