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Volumn 128, Issue 33, 2006, Pages 10868-10875

Rapid energy transfer in cascade-type bodipy dyes

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; BORON; ELECTRIC EXCITATION; ENERGY TRANSFER; FLUORESCENCE; MOLECULAR DYNAMICS; POLYMERS;

EID: 33747752533     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0631448     Document Type: Article
Times cited : (141)

References (59)
  • 24
    • 33747785699 scopus 로고    scopus 로고
    • U.S. Patent 5,451,663, Sept 19, 1995
    • Kang, H. C.; Haugland, R. P. U.S. Patent 5,451,663, Sept 19, 1995.
    • Kang, H.C.1    Haugland, R.P.2
  • 45
    • 0141622587 scopus 로고    scopus 로고
    • Aceelrys Software Inc.: Cambridge, UK
    • INSIGHT-II; Aceelrys Software Inc.: Cambridge, UK, 2001-2006.
    • (2001) INSIGHT-II
  • 52
    • 33747749600 scopus 로고    scopus 로고
    • note
    • The oxidation and reduction potentials, respectively, for the first excited singlet state of the Bodipy unit are calculated to be -1.55 and 0.82 V vs SCE. On this basis, we can rule out light-induced electron-transfer processes involving the Bodipy excited state and either of the polycycles. The reduction potential for the excited singlet state of the perylene unit is calculated to be 0.89 V vs SCE, such that this species might be expected to oxidize the Bodipy unit (ΔG° = -0.08 eV, ignoring electrostatic effects). The corresponding oxidation potential for the perylene unit is -1.73 V vs SCE, such that reduction of the Bodipy unit is a possibility (ΔG° = -0.19 eV, ignoring electrostatic effects). For pyrene, the oxidation potential for the excited singlet state is estimated to be -1.89 V vs SCE, such that, in principle, this species might be expected to reduce both the Bodipy (ΔG° = -0.35 eV) and perylene (ΔG° = -0.13 eV) units.
  • 56
    • 84891026017 scopus 로고    scopus 로고
    • Haley, M. M., Tykwinski, R. R., Eds.; Wiley-VCH: Weinheim
    • Harriman, A.; Ziessel, R. In Carbon-Rich Compounds; Haley, M. M., Tykwinski, R. R., Eds.; Wiley-VCH: Weinheim, 2006; p 26.
    • (2006) Carbon-Rich Compounds , pp. 26
    • Harriman, A.1    Ziessel, R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.