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Although these pyrenes and anthracenes are previously known (Ref. 9) and both BDMAP (Refs. 6,7d) and DMA (Ref. 7a,h) have been used for some PET reactions, PET reactions of DMP and BDMAA have not been reported. In addition, no systematic study on the utilities of these four compounds as sensitizers for PET reactions has been conducted.
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red in V vs SCE) of some representative substrates are -1.59 V for 1a, -1.82 V for 3, and -1.78 V for 7, respectively. In the cases of 1b, 1c, and 5a, the reduction peaks were not observed below -2.3 V.
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57
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33747031934
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note
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In principle, a polar solvent accelerates initial PET processes (Refs. 3,15,17), and is desirable for a PET reaction involving sensitization. However, if a reaction requires a chemical process within a radical ion pair, e.g., proton transfer from a radical cation to a radical anion (Ref. 17), nonpolar solvents are in some cases more favorable to lead better yields of products as compared to polar solvents (Ref. 10e). Therefore, a choice of a suitable solvent for each case is important for preparative PET reactions.
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