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Volumn 45, Issue 7, 2006, Pages 1089-1092

Spectroscopic characterization of reaction intermediates in a model for copper nitrite reductase

Author keywords

Bioinorganic chemistry; Copper; Enzyme models; Reaction mechanisms; Reactive intermediates

Indexed keywords

BIOINORGANIC CHEMISTRY; ENZYME MODELS; PROTONATION; REACTIVE INTERMEDIATES;

EID: 33746323645     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200503555     Document Type: Article
Times cited : (39)

References (29)
  • 2
    • 2742559094 scopus 로고
    • Eds.: K. D. Karlin, Z. Tyeklár, Chapman & Hall, New York
    • b) E. T. Adman, S. K. Turley in Bioinorganic Chemistry of Copper (Eds.: K. D. Karlin, Z. Tyeklár), Chapman & Hall, New York, 1993, pp. 397-405;
    • (1993) Bioinorganic Chemistry of Copper , pp. 397-405
    • Adman, E.T.1    Turley, S.K.2
  • 24
    • 33746322848 scopus 로고    scopus 로고
    • note
    • [6,7], 2 equivalents of TFA are required to complete the reaction. According to EPR analysis, about 70% of NO gas is trapped by iron(II) octaethylporphyrin complex in this reaction.
  • 25
    • 33746279166 scopus 로고    scopus 로고
    • note
    • 6Cu: C 41.87, H 6.10, N 7.71; found: C 41.62, H 5.99, N 7.63.
  • 26
    • 33746276509 scopus 로고    scopus 로고
    • note
    • -1).
  • 29
    • 33746294436 scopus 로고    scopus 로고
    • note
    • The small red shift (3 nm) of the absorption peak may be induced by THF or TFA in the solvent.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.