Importance of entropy in the diastereoselectivity of 5-substituted 2-methyladamant-2-yl cations

Journal of Organic Chemistry

Volumn 69, Issue 17, 2004, Pages 5537-5546

  Filippi, Antonello ^a   Trout, Neil A ^b   Brunelle, Patrick ^c   Adcock, William ^b   Sorensen, Ted S ^c   Speranza, Maurizio ^a  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

^b FLINDERS UNIVERSITY   (Australia)

^c UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; ELECTRONIC PROPERTIES; ENTHALPY; ENTROPY; METHANOL; POSITIVE IONS; STEREOCHEMISTRY; SUBSTITUTION REACTIONS;

DIASTEREOSELECTIVITY; ENERGY SURFACE;

ORGANIC CHEMICALS;

2 METHYLADAMANT 2 YL DERIVATIVE; AMANTADINE DERIVATIVE; BENZYL DERIVATIVE; BROMIDE; CATION; CHLORIDE ION; CYANIDE; ESTER; METHANOL; METHOXY GROUP; METHYL GROUP; OXYGEN 18; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; DIASTEREOISOMER; ENERGY; ENTHALPY; ENTROPY; EPIMERIZATION; GAS; PRESSURE; RADIOLYSIS; STEREOCHEMISTRY; TEMPERATURE; THERMODYNAMICS;

EID: 4043052107     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo049481l     Document Type: Article

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