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55
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33746188414
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note
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[15]
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56
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0036569913
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+) was reported: R. Shenhar, H. Wang, R. E. Hoffman, L. Frish, L. Avram, I. Willner, A. Rajca, M. Rabinovitz, J. Am. Chem. Soc. 2002, 124, 4685.
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57
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33746249139
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note
-
8]THF (≈ 0.5 mL) was distilled from a reservoir into the tube. The sample was degassed under vacuum by the freeze-pump-thaw technique and flame-sealed. For lithium samples the same procedure was conducted, except that a freshly produced lithium wire was immediately inserted into the upper part of an extended NMR tube. For several of the lithium samples, a small amount of corannulene was previously added to the tube. Controlled reductions of the samples were carried out by inverting the tubes at low temperature (-30°C) to bring the solutions into contact with the alkali metals. Returning the tubes to their upright positions stopped reductions from progressing.
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58
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33746212028
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note
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6- with iodine does not form a new, clean diamagnetic species; rather, it results in apparent polymerization.
-
-
-
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59
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33746188412
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note
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1H NMR spectroscopy.
-
-
-
-
60
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0032127481
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-
The use of corannulene as an effective "electron shuttle" has been shown: E. Shabtai, A. Weitz, R. C. Haddon, R. E. Hoffman, M. Rabinovitz, A. Khong, R. J. Cross, M. Saunders, P.-C. Cheng, L. T. Scott, J. Am. Chem. Soc. 1998, 120, 6389.
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Saunders, M.8
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Scott, L.T.10
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61
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33746235956
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note
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1H NMR spectroscopy.
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-
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62
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33746235957
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note
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6-, aside from the formation of additional aggregates. See text.
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63
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33746249138
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note
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Only after weeks of charging at room temperature is a new diamagnetic species formed.
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64
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33746249140
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note
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[33-35]
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65
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0004171599
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Wiley-VCH, Weinheim
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Hexakis(4-n-dodecylbiphenylyl)benzene hexaanion: L. Eshdat, R. E. Hoffman, A. Fechtenkötter, K. Müllen, M. Rabinovitz, Chem. Eur. J. 2003, 9, 1844.
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See also: A. Minsky, A. Y. Meyer, M. Rabinovitz, Tetrahedron Lett. 1982, 23, 5351.
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0001707134
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See, for example a) J. Klein, Tetrahedron 1983, 39, 2733;
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33746235954
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note
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13C NMR shifts, as explained in text and reference [27].
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96
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33746188396
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c) A. Ayalon, Ph.D. Thesis, The Hebrew University of Jerusalem, 1993.
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Ayalon, A.1
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105
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33746188406
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note
-
This tetrameric model was found computationally to be an energy minimum. Unfortunately, semiempirical methods, as implemented in Spartan02 (AM1, PM3, and MNDO) do not handle potassium, and the system is too large to calculate with even higher levels of theory (e.g., ab initio and DFT).
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