η6-corannulene buckybowl complexes of iridium, including ring-to-ring migration

Organometallics

Volumn 22, Issue 4, 2003, Pages 624-626

  Alvarez, Celedonio M ^a   Angelici, Robert J ^a   Sygula, Andrzej ^a   Sygula, Renata ^a   Rabideau, Peter W ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CORANNULENE; RING TO RING MIGRATION; TETRAMETHYLCORANNULENE COMPLEX;

ACETONE; COMPLEXATION; IRIDIUM COMPOUNDS; ISOMERS; MOLECULAR STRUCTURE; SURFACES; SYNTHESIS (CHEMICAL);

FULLERENES;

EID: 0037450836     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om021012r     Document Type: Article

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18. 10, 2H), 2.06 (s, Cp*, 15H) ppm.
19. 2, room temperature): δ 143.7 (C4,9), 134.1 (C6,7), 131.8 (C5,8), 121.1 (C3,10), 115.1 (C-Ir), 105.0 (Cp*), 99.4 (C-Ir), 92.4 (C1,2), 9.98 (Cp*Me), 144.6, 136.6, 136.0, 134.6 (C4a, C6a, C8a, C10d, C10e, C10f) ppm.
20. 4, 3H), 1.89 (s, Cp*, 15H) ppm.
21. 4, 6H) 2.02 (s, Cp* 15H) ppm.
22. 4, 6H), 2.03 (s, Cp*, 15H) ppm.
23. 2, room temperature): δ 143.4 (C9), 141.8 (C4), 132.5 (C7), 131.7 (C8), 119.8 (C3), 119.6 (C10), 115.7 (C-Ir), 114.6 (C-Ir), 107.3 (C-Ir), 106.9 (C-Ir), 103.5 (Cp*), 98.8 (C-Ir), 98.3 (C-Ir), 16.2 (Me), 15.6 (Me), 14.8 (Me), 9.27 (Cp*Me), 142.7, 142.6, 139.9, 137.1, 136.2, 135.0, 134.1 (C5, C6, C4a, C6a, C8a, C10d, C10e, C10f) ppm.
24. 2.