Catalytic epoxypolyene cyclization via radicals: A simple total synthesis of sclareol oxide and its 8-epimer

Synthesis

Volumn , Issue 13, 2006, Pages 2151-2154

  Gansäuer, Andreas ^a   Worgull, Dennis ^a   Justicia, José ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

Catalysis; Epoxypolyene cyclization; Natural products; Radicals; Titanocene

Indexed keywords

AROMATIZATION; CATALYSIS; CHEMICAL MODIFICATION; OLEFINS; REACTION KINETICS; SYNTHESIS (CHEMICAL);

EPOXYPOLYENE CYCLIZATION; NATURAL PRODUCTS; RADICALS; TITANOCENE;

ACETONE;

ACETONE; ALKENE; EPOXIDE; EPOXYFARNESYL ACETONE; NATURAL PRODUCT; POLYENE; SCLAREOL; SCLAREOL OXIDE; UNCLASSIFIED DRUG; XANTHIC ACID DERIVATIVE;

ACETALIZATION; ARTICLE; CATALYSIS; COLUMN CHROMATOGRAPHY; CYCLIZATION; DEOXYGENATION; DIASTEREOISOMER; ELIMINATION REACTION; ENANTIOMER; EPOXIDATION; HYDROXYLATION; STEREOCHEMISTRY;

EID: 33746083184     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-942406     Document Type: Article

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