Emergence of a novel catalytic radical reaction: Titanocene-catalyzed reductive opening of epoxides

Journal of the American Chemical Society

Volumn 120, Issue 49, 1998, Pages 12849-12859

  Gansäuer, Andreas ^a   Bluhm, Harald ^a   Pierobon, Marianna ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; EPOXIDE; ORGANOMETALLIC COMPOUND; OXYGEN; RADICAL; TITANIUM; TITANOCENE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CYCLIZATION; ELECTRON TRANSPORT; PROTON TRANSPORT;

EID: 0032539234     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja981635p     Document Type: Article

References (9)

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3. (a) Beckwith, A. L. J.; Easton, C. J.; Serelis, A. K. J. Chem. Soc., Chem. Commun. 1980, 482.
4. (b) Smadja, W. Synlett 1994, 1.
5. (c) Curran, D. P.; Porter, N. A.; Giese, B. Stereochemistry of Radical Reactions; VCH: Weinheim, 1996.
6. Fürstner, A., Ed. Active Metals; VCH: Weinheim, 1996.
7. Grisenti, P.; Ferraboschi, P.; Casati, S.; Santaniello, E. Tetrahedron Asymmetry 1993, 4, 997.
8. Gill, M.; Smredel, A. F. Tetrahedron Asymmetry 1990, 1, 453.
9. Temnikowa, T. I.; Semenowna, S. N. J. Org. Chem. USSR (Engl. Transi.) 1966, 2, 1171.