Conformationally controlled (entropy effects), stereoselective vibrational quenching of singlet oxygen in the oxidative cleavage of oxazolidinone-functionalized enecarbamates through solvent and temperature variations

Tetrahedron

Volumn 62, Issue 28, 2006, Pages 6707-6717

  Sivaguru, J ^a   Solomon, Marissa R ^a   Saito, Hideaki ^a,c,d   Poon, Thomas ^e   Jockusch, Steffen ^a   Adam, Waldemar ^f,g   Inoue, Yoshihisa ^c,d   Turro, Nicholas J ^a,b  

^a Och Spine at New York Presbyterian Hospitals   (United States)

^b Osaka University ^*  (United States)

^c OSAKA UNIVERSITY   (Japan)

^d JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^e KECK GRADUATE INSTITUTE   (United States)

^f UNIVERSITY OF WÜRZBURG   (Germany)

^g UNIVERSITY OF PUERTO RICO RIO PIEDRAS   (Puerto Rico)

Author keywords

Chiral auxiliary; Conformational effects; E Z isomers; Mechanism; Photooxygenation; Stereoselectivity; Substituent effects; Vibrational quenching

Indexed keywords

CARBAMIC ACID DERIVATIVE; OXAZOLIDINONE DERIVATIVE; SINGLET OXYGEN; SOLVENT;

ARTICLE; CONFORMATION; DEGRADATION; ENANTIOMER; ENTROPY; OXIDATION; PRIORITY JOURNAL; STEREOCHEMISTRY; TEMPERATURE SENSITIVITY; VIBRATION;

EID: 33744944763     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2006.01.119     Document Type: Article

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