Stereocontrol within confined spaces: Enantioselective photooxidation of enecarbamates inside zeolite supercages

Journal of the American Chemical Society

Volumn 126, Issue 35, 2004, Pages 10816-10817

  Sivaguru, J ^a   Poon, Thomas ^b   Franz, Roberto ^a   Jockusch, Steffen ^a   Adam, Waldemar ^c,d   Turro, Nicholas J ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

^b KECK GRADUATE INSTITUTE   (United States)

^c UNIVERSITY OF PUERTO RICO   (Puerto Rico)

^d UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBAMIC ACID DERIVATIVE; CATION; ENECARBAMATE; METHYLENE BLUE; UNCLASSIFIED DRUG; ZEOLITE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; ENANTIOSELECTIVITY; PHOTOOXIDATION; PHOTOREACTIVITY; STEREOCHEMISTRY;

EID: 4444220353     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046115a     Document Type: Article

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23. See Supporting Information for details.
24. Photobleaching of the singlet-oxygen sensitizers, as well as the decrease of the mass balance due to decomposition of the photoproducts, was noticed during the prolonged photooxidation of alkenes within zeolites (ref 8).
25. Large cation-exchanged zeolites such as KY, RbY, and CsY were not examined as there was poor loading of the enecarbamates Z/E-1.
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