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See refs 4a, 4b, and 4d.
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18
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0011214278
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For a synthesis of ent-3 see: Rudchenko, V. F.; Shtamburg, V. G.; Pleshkova, A. P.; Kostyanovskii, R. G. Bull Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.) 1981, 30, 825.
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0000862469
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This result can be explained by a stereoelectronically controlled axial allylation of the intermediate oxocarbenium ion in a boatlike transition state assembly. Pansare, S. V.; Ravi, R. G.; Jain, R. P. J. Org. Chem. 1998, 63, 4120.
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10944272081
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22
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33744761906
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note
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Determined by HPLC analysis on a Chiralpak AD-H column; see the Supporting Information for details.
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24
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0000885877
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