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Volumn 12, Issue 14, 2006, Pages 3905-3915

Intramolecular photoarylation of alkenes by phenyl cations

Author keywords

Aryl cations; Arylation; C C coupling; Cyclization photochemistry

Indexed keywords

BUTENES; CHLORINATED RUBBER PAINT; IRRADIATION; PHOTOCHEMICAL REACTIONS; POSITIVE IONS; REACTION KINETICS; SOLVENTS;

EID: 33646517724     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200501392     Document Type: Article
Times cited : (31)

References (77)
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    • (2005) Angew. Chem. Int. Ed. , vol.44 , pp. 5675-5678
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    • note
    • As an example, in MeCN the consumption of 1 in 17 h was approximately 27% in an unsensitized experiment compared to total consumption when acetone was used.
  • 27
    • 3042825501 scopus 로고    scopus 로고
    • For related synthesis of compound 18 under radical conditions, see: a) D. Stien, S. Gastaldi, J. Org. Chem. 2004, 69, 4464-4470;
    • (2004) J. Org. Chem. , vol.69 , pp. 4464-4470
    • Stien, D.1    Gastaldi, S.2
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    • note
    • [16] or 0.52.[21]
  • 31
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    • note
    • 2-Chloroanisole was photoreduced in methanol with a quantum yield of 0.14.[16]
  • 38
    • 0000118297 scopus 로고
    • endo measured for the cyclization of an aryl radical onto an O-allyl or a butenyl was about 100 and 50 respectively. See: H. Togo, O. Kikuchi, Heterocycles 1989, 28, 373-379.
    • (1989) Heterocycles , vol.28 , pp. 373-379
    • Togo, H.1    Kikuchi, O.2
  • 57
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    • The photo-Claisen rearrangement (see for example A. L. Pincock, J. A. Pincock, R. Stefanova, J. Am. Chem. Soc. 2002,124, 9768-9778) occurs only after that the chloride has been lost, see the formation of 31 by irradiation of 32.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 9768-9778
    • Pincock, A.L.1    Pincock, J.A.2    Stefanova, R.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.