Radical Cyclization of Allyl 2-Iodophenyl Ether, N,N-Diallyl-2-iodoaniline, and 2-Iodoethanal Acetal by Means of Trialkylmanganate(II)

Bulletin of the Chemical Society of Japan

Volumn 70, Issue 9, 1997, Pages 2039-2049

  Inoue, Rie ^a   Nakao, Junko ^a   Shinokubo, Hiroshi ^a   Oshima, Koichiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000514081     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.70.2039     Document Type: Article

References (67)

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52. 2 afforded only the reduced product, phenyl prenyl ether, or N,N-diprenylaniline in 20 or 30% yield along with the recovered starting materials.
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65. In contrast to the catalytic reaction of 1a, in which the presence of oxygen was essential, the catalytic reaction of 11 was complete in 3 h at 0 °C under argon atmosphere in a sealed system. Thus, single electron transfer from zero-valent manganese to 2-iodoethanal acetal would provide alkyl radical and manganese(I) species as shown below (Chart 2). Chemical equations presented
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