메뉴 건너뛰기




Volumn 128, Issue 15, 2006, Pages 4940-4941

Highly enantioselective addition of Me2Zn to aldehydes catalyzed by ClCr(Salen)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; BENZALDEHYDE; CHROMIUM DERIVATIVE; METHYL GROUP; ORGANOMETALLIC COMPOUND; ZINC DERIVATIVE;

EID: 33646138506     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057969d     Document Type: Article
Times cited : (61)

References (36)
  • 32
    • 28544452446 scopus 로고    scopus 로고
    • An important green chemistry approach to more efficient asymmetric reactions was reported by Walsh, see: Jeon, S.-J.; Li, H.; Walsh, P. J. J. Am. Chem. Soc. 2005, 127, 16416-16425.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 16416-16425
    • Jeon, S.-J.1    Li, H.2    Walsh, P.J.3
  • 33
    • 33646151103 scopus 로고    scopus 로고
    • note
    • Linear aliphatic aldehydes were also tested; Hydrocinnamic aldehyde gives 86% ee, and octanal gives 81% ee. With cyclohexanecarboxaldehyde (Table 2, entry 12, 68% yield) only unreacted aldehyde and the desired product were observed by GC/MS and TLC after quenching.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.