A new cysteine-derived ligand as catalyst for the addition of diethylzinc to aldehydes: The importance of a 'free' sulfide site for enantioselectivity

Synthesis

Volumn , Issue 4, 2005, Pages 588-594

  Braga, Antonio L ^a   Alves, Elenilson F ^a   Silveira, Claudio C ^a   Zeni, Gilson ^a   Appelt, Helmoz R ^b   Wessjohann, Ludger A ^c  

^a FEDERAL UNIVERSITY OF SANTA MARIA   (Brazil)

^b CENTRO UNIVERSITÁRIO FRANCISCANO   (Brazil)

^c LEIBNIZ INSTITUTE OF PLANT BIOCHEMISTRY   (Germany)

Author keywords

Asymmetric synthesis; Chiral ligands; Cysteine; Dialkylzinc; Disulfide

Indexed keywords

ADDITION REACTIONS; ALCOHOLS; ALDEHYDES; ALKYLATION; CATALYSIS; CHEMICAL BONDS; DERIVATIVES; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

ALKYLATED SULFIDE LIGAND; CHIRAL SULFIDE; CYSTEIN-DERIVED LIGAND; SECONDARY ALCOHOLS;

SULFUR COMPOUNDS;

ALDEHYDE; BENZYL ALCOHOL; CYSTEINE; DIETHYLZINC; LIGAND; NITROGEN; OXYGEN; SULFIDE; SULFUR;

ADDITION REACTION; ALKYLATION; ARTICLE; ATOMIC PARTICLE; CATALYST; CHIRALITY; ENANTIOSELECTIVITY; REACTION ANALYSIS; SYNTHESIS;

EID: 15444369094     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-861801     Document Type: Article

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