Kinetic modeling of glycerolysis-hydrolysis of canola oil in supercritical carbon dioxide media using equilibrium data

Journal of Supercritical Fluids

Volumn 37, Issue 3, 2006, Pages 417-424

  Moquin, Paul H L ^a   Temelli, Feral ^a   Sovová, Helena ^b   Saldaña, Marleny D A ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

^b INSTITUTE OF CHEMICAL PROCESS FUNDAMENTALS   (Czech Republic)

Author keywords

Canola oil; Glycerolysis; Hydrolysis; Kinetics; Monoglycerides; Supercritical media

Indexed keywords

ALCOHOLS; CARBON DIOXIDE; CATALYSTS; HYDROLYSIS; IONIZATION; REACTION KINETICS; SUPERCRITICAL FLUID EXTRACTION; THIN LAYER CHROMATOGRAPHY;

CANOLA OIL; GLYCEROLYSIS; MONOGLYCERIDES; SUPERCRITICAL MEDIA;

OILS AND FATS;

EID: 33646093015     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2006.01.009     Document Type: Article

References (18)

1. Temelli F., King J.W., and List G.R. Conversion of oils to monoglycerides by glycerolysis in supercritical carbon dioxide media. J. Am. Oil Chem. Soc. 73 (1996) 699-706
2. Jackson M.A., and King J.W. Lipase-catalyzed glycerolysis of soybean oil in supercritical carbon dioxide. J. Am. Oil Chem. Soc. 74 (1997) 103-106
3. Sonntag N.O.V. Glycerolysis of fats and methyl-esters - status, review and critique. J. Am. Oil Chem. Soc. 59 (1982) A795-A802
4. Li Z.Y., and Ward O.P. Lipase-catalyzed esterification of glycerol and n-3 polyunsaturated fatty-acid concentrate in organic-solvent. J. Am. Oil Chem. Soc. 70 (1993) 745-748
5. Flickinger B.D., and Matsuo N. Nutritional characteristics of DAG oil. Lipids 38 (2003) 129-132
6. Tada N., Shoji K., Takeshita M., Watanabe H., Yoshida H., Hase T., Matsuo N., and Tokimitsu I. Effects of diacylglycerol ingestion on postprandial hyperlipidemia in diabetes. Clin. Chim. Acta 353 (2005) 87-94
7. Takase H., Shoji K., Hase T., and Tokimitsu I. Effect of diacylglycerol on postprandial lipid metabolism in non-diabetic subjects with and without insulin resistance. Atherosclerosis 180 (2005) 197-204
8. Noureddini H., Harkey D.W., and Gutsman M.R. A continuous process for the glycerolysis of soybean oil. J. Am. Oil Chem. Soc. 81 (2004) 203-207
9. Moquin P.H.L., Temelli F., King J.W., and Palcic M.M. Kinetic modeling of the glycerolysis reaction for soybean oil in supercritical carbon dioxide media. J. Am. Oil Chem. Soc. 82 (2005) 613-617
10. Indrasena W.M., Henneberry K., Barrow C.J., and Kralovec J.A. Qualitative and quantitative analysis of lipid classes in fish oils by thin-layer chromatography with an iatroscan flame ionization detector (TLC-FID) and liquid chromatography with an evaporative light scattering detector (LC-ELSD). J. Liq. Chromatogr. Relat. Technol. 28 (2005) 2581-2595
11. Stephens R.D., Mulawa P.A., Giles M.T., Kennedy K.G., Groblicki P.J., Cadle S.H., and Knapp K.T. An experimental evaluation of remote sensing-based hydrocarbon measurements: a comparison to FID measurements. J. Air Waste Manage. Assoc. 46 (1996) 148-158
12. Siemens B.J., and Daun J.K. Determination of the fatty acid composition of canola, flax, and solin by near-infrared spectroscopy. J. Am. Oil Chem. Soc. 82 (2005) 153-157
13. Wright A.J., McGauley S.E., Narine S.S., Willis W.M., Lencki R.W., and Marangoni A.G. Solvent effects on the crystallization behavior of milk fat fractions. J. Agric. Food Chem. 48 (2000) 1033-1040
14. SAS Institute Inc., Version 9.1, Cary, NC, 2003.
15. D.G. Hyams, CurveExpert Version 1.37, Chadwick Court, Hixson, TN, 2001.
16. Lasdon L., and Allan W. Microsoft Excel Solver (GRG2) (2002), Frontline Systems Inc., Incline Village, NV
17. Vick Roy J.R., and Converse A.O. Biomass Hydrolysis with Sulfur Dioxide and Water in the Region of the Critical Point (1985), Elsevier Science Publishers, B.V., Amsterdam, The Netherlands
18. Kashulines P., Rizvi S.S.H., Harriott P., and Zollweg J.A. Viscosities of fatty acids and methylated fatty acids saturated with supercritical carbon dioxide. J. Am. Oil Chem. Soc. 68 (1991) 912-921