3D-NMR studies of B-centered n-ad structures in poly(ethylene-co- 13C-n-butyl acrylate-co-carbon monoxide)

Macromolecules

Volumn 39, Issue 8, 2006, Pages 2886-2899

  Monwar, Masud ^a   Sahoo, Sangrama K ^a   McCord, Elizabeth F ^b   Arthur, Samuel D ^b   Walsh, David J ^b   Rinaldi, Peter L ^a  

^a UNIVERSITY OF AKRON   (United States)

^b DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC CONNECTIVITY INFORMATION; HYDROCARBON-BASED TERPOLYMERS;

CARBON; CARBON MONOXIDE; HYDROCARBONS; HYDROGEN; MONOMERS; NUCLEAR MAGNETIC RESONANCE; ORGANIC POLYMERS; RESONANCE; TERPOLYMERS;

MICROSTRUCTURE;

EID: 33646056089     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma052572f     Document Type: Article

References (39)

1. Randall, J. C. J. Macromol. Sci., Rev. Macromol. Chem. Phys. 1989, C29, 201.
2. Bruch, M. D.; Payne, W. G. Macromolecules 1986, 19, 2712.
3. Liu, W.; Ray, D. G., III.; Rinaldi, P. L.; Zens, T. J. Magn. Reson. 1999, 140, 482.
4. Liu, W.; Rinaldi, P. L.; McIntosh, L. H.; Quirk, R. P. Polym. Prepr. (Am. Chem. Soc., Din. Polym. Chem.) 2000, 41, 30.
5. Sahoo, S. K.; Zhang, T.; Dudipala, V. R.; Rinaldi, P. L.; McIntosh, L. H.; Quirk, R. P. Macromolecules 2003, 36, 4017.
6. McCord, E. F.; Shaw, W. H., Jr.; Hutchinson, R. A. Macromolecules 1997, 30, 246.
7. Rinaldi, P. L. In NMR Spectroscopy of Polymers in Solution and in the Solid State; Cheng, H. N., English, A. D., Eds.; ACS Symposium Series 834; American Chemical Society: Washington, DC, 2003; Chapter 8, p 94.
8. Rinaldi, P. L. Analyst 2004, 129, 687.
9. Rinaldi, P. L.; Ray, D. G., III; Li, L.; Wang, H. T.; Harwood, H. J. Multidimensional Spectroscopy of Polymers; Urban, M. W., Provder, T., Eds.; ACS Symposium Series 598; American Chemical Society: Washington, DC, 1995; Chapter 13.
10. Li, L.; Ray, D.; Wang, H. T.; Harwood, H. J.; Rinaldi, P. L. Macromolecules 1996, 29, 4706.
11. Rinaldi, P. L.; Ray, D. G., III; Li, L.; Wang, H. T.; Harwood, H. J. Polym. Mater. Sci. Eng. 1994, 71, 269.
12. Li, L.; Rinaldi, P. L. Macromolecules 1996, 29, 4808.
13. Li, L.; Rinaldi, P. L. Macromolecules 1997, 30, 520.
14. Saito, T.; Medsker, R. E.; Harwood, H. J.; Rinaldi, P. L. J. Magn. Reson. A 1996, 120, 125.
15. Liu, W.: Saito, T.; Li, L.; Rinaldi, P. L.; Hirst, R.; Halasa, A. F.; Visintainer, J. Macromolecules 2000, 33, 2364.
16. Liu, W.; Rinaldi, P. L.; Galya, L.; Hansen, J. E.; Wilczek, L. Organometallics 2002, 21, 3250.
17. Chai, M.; Tessier, C.; Rinaldi, P. L. J. Am. Chem. Soc. 1999, 121, 273.
18. Sahoo, S. K.; McCord, E. F.; Rinaldi, P. L. J. Magn. Reson. 2004, 168, 352.
19. Patt, S. L. J. Magn. Reson. 1992, 96, 94.
20. Note that n-ad sequences in vinyl polymers normally are structurally indistinguishable if the order of monomer addition is reversed; however, this is not the case with these polymers containing units from carbon monoxide, which contributes only one carbon to the polymer backbone.
21. Wyzgoski, F. J.; Rinaldi, P. L.; McCord, E. F.; Stewart, M. A.; Marshall, D. R. Macromolecules 2004, 37, 846.
22. Monwar, M.; Oh, S. J.; Rinaldi, P. L.; McCord, E. F.; Hutchinson, R. A.; Buback, M. M.; Latz, H. J. Anal. Bioanal. Chem. 2004,378, 1414.
23. Al-Amri, A.; Monwar, M.; McCord, E. F.; Buback, M.; Latz, H.; Rinaldi, P. L. Macromolecules, submitted for publication.
24. Bodenhausen, G.; Ruben, D. J. Chem. Phys. Lett. 1980, 69, 565.
25. Bax, A.; Summers, M. F. J. Am. Chem. Soc. 1986, 108, 2093.
26. Shaka, A. J.; Barker, P. B.; Freeman, R. J. Magn. Reson. 1985, 64, 547.
27. States, D. J.; Haberkorn, R. A.; Ruben, D. J. J. Magn. Reson. 1985, 64, 547.
28. Monwar, M.; Sahoo, S. K.; Rinaldi, P. L.; McCord, E. F.; Marshall, D. R.; Buback, M.; Latz, H. Macromolecules 2003, 36, 6695.
29. Marion, D.; Ikura, M.; Tschudin, R.; Bax, A. J. Magn. Reson. 1989, 85, 393.
30. Kay, L. E.; Keiffer, P.; Saarinen, T. J. Am. Chem. Soc. 1992, 114, 10663.
31. Xia, Y.; Kong, X.; Smith, D. K.; Liu, Y.; Man, D.; Zhu, G. J. Magn. Reson. 2000, 143, 407.
32. Shaka, A. J.; Lee, C. J.; Pines, A. J. Magn. Reson. 1988, 77, 274.
33. The Bernoullian probabilities are listed only as a rough guide to qualitatively describe the relative amounts of pentads; it is not meant to imply that the reactivities of the three monomers are equal.
34. Carman, C. J.; Wilkes, C. E. Rubber Chem. Technol. 1971, 44, 781.
35. Dorman, D. E.; Otocka, E. P.; Bovey, F. A. Macromolecules 1972, 5, 574.
36. In this case, the term "branch" is used loosely, and the branch unit is formed by the replacement of the backbone methylene hydrogens with an oxygen atom.
37. Morris, G. A.; Freeman, R. J. Am. Chem. Soc. 1979, 101, 760.
38. Rama Krishna, N.; Berliner, L. J. Protein NMR for the Millennium. Biological Magnetic Resonance; Kluwer Academic/Plenum Publishers: New York, 2003; Vol. 20.
39. See Supporting Information.