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note
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The proposed system of nomenclature is necessary to distinguish structures associated with resonances that are better resolved using high-field NMR instruments. Labeling the backbone carbon permits assignment of unique identifiers, especialy for nonequivalent structures (e.g., BEC and CEB), which can be correlated to their distinctive NMR resonances.
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22
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1342320824
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note
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In this case, the term "branch" is used loosely, and the branch unit is formed by the replacement of the backbone methylne C-H bonds with a C=O bond.
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1342278487
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note
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All assignments are based on the 2D-NMR data of polyBCE collected in this research. Comparisons to literature chemical shifts of model polymers are described in the text to support these assignments. Prior results were generally obtained in different solvents under different conditions so that chemical shifts do not necessarily agree.
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