Zn(tbip) (H2tbip= 5-tert-butyl isophthalic acid): A highly stable guest-free microporous metal organic framework with unique gas separation capability

Journal of the American Chemical Society

Volumn 128, Issue 13, 2006, Pages 4180-4181

  Pan, Long ^a   Parker, Brett ^a   Huang, Xiaoying ^a   Olson, David H ^a   Lee, JeongYong ^a   Li, Jing ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

5 TERT BUTYL ISOPHTHALIC ACID; DIMETHYL ETHER; ISOPHTHALIC ACID; METAL; METHANOL; ORGANIC COMPOUND; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

ADSORPTION; ARTICLE; CRYSTAL STRUCTURE; DESORPTION; GAS ANALYSIS; HEAT; MOLECULAR INTERACTION; MOLECULAR STABILITY; POLYMERIZATION; POROSITY; PRESSURE; SEPARATION TECHNIQUE; TEMPERATURE; THERMOGRAVIMETRY; THERMOSTABILITY; X RAY POWDER DIFFRACTION;

EID: 33645466127     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057667b     Document Type: Article

References (25)

1. (a) Pan, L.; Adams, K. M.; Hernandez, H. E.; Wang, X.; Zheng C.; Hattori, Y.; Kaneko, K. J. Am. Chem. Soc. 2003, 125, 3063.
2. (b) Matsuda, R.; Kitaura, R.; Kitagawa, S.; Kubota, Y.; Belosludov, R. V.; Kobayashi, R. C.; Sakamoto, H.; Chiba, T.; Takata, M.; Kawazoe, Y.; Mita, Y. Nature 2005, 436, 238.
3. (c) Pan, L.; Olson, D. H.; Ciemnolonski, L. R.; Heddy, R.; Huang, X.-Y.; Li, J. Angew. Chem., Int. Ed. 2006, 45, 616.
4. (a) Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keeffe, M.; Yaghi, O. M. Science 2003, 300, 1127.
5. (b) Pan, L.; Sander, M. B.; Huang, X.-Y.; Li, J.; Smith, M.; Bittner, E.; Bockrath, B.; Johnson J. K. J. Am. Chem. Soc. 2004, 126, 1308.
6. (c) Rowsell, J. L. C.; Millward, A. R.; Park, K. S.; Yaghi, O. M. J. Am. Chem. Soc. 2004, 126, 5666.
7. (d) Dincã, M.; Long, J. R. J. Am. Chem. Soc. 2005, 127, 9376.
8. (e) Kesanli, B.; Cui, Y.; Smith, M. R.; Bittner, E. W.; Bockrath, B. C.; Lin, W. B. Angew Chem. 2005, 44, 72.
9. (f) Lee, J.-Y.; Pan, L.; Kelly, S. K.; Jagiello, J.; Emge, T. J.; Li, J. Adv. Mater. 2005, 17, 2703.
10. (g) Lee, J.-Y.; Jagiello, J.; Li, J. J. Solid State Chem. 2005, 178, 2572.
11. (h) Rowsell, J. L. C.; Yaghi, O. M. Angew. Chem., Int. Ed. 2005, 44, 4670.
12. (i) Zhao, X.; Xiao, B.; Fletcher, A. J.; Thomas, K. M.; Bradshaw, D.; Rosseinsky, M. J. Science 2004, 306, 1012.
13. (j) Lee, E. Y.; Jang, S. Y.; Suh, M. P. J. Am. Chem. Soc. 2005, 127, 6374.
14. (k) Kubota, Y.; Takata, M.; Matsuda, R.; Kitaura, R.; Kitagawa, S.; Kato, K.; Sakata, M.; Kobayashi, T. C. Angew Chem. 2005, 44, 920.
15. Chun, H.; Dybtsev, D. N.; Kim, H.; Kim, K. Chem.-Eur. J. 2005, 11, 3521.
16. (m) Dybtsev, D. N.; Chun, H.; Yoon, S. H.; Kim, D.; Kim, K. J. Am. Chem. Soc. 2004, 126, 32.
17. (n) Kaye, S. S.; Long, J. R. J. Am. Chem. Soc. 2005, 127, 6506.
18. (o) Dinca, M.; Long, J. R. J. Am. Chem. Soc. 2005, 127, 9376.
19. (p) Férey, G.; Latroche, M.; Serre, C.; Millange, F.; Loiseau, T.; Percheron-Guégan, A. Chem. Commun. 2003, 2976.
20. (q) Dubinin, M. M.; Astakhov, V. A. Adv. Chem. Ser. 1971, 102, 69.
21. -1): 3448 (br), 2994 (vs), 2974 (s), 1621 (vs), 1544 (vs), 1433 (s), 1417 (s), 1376 (vs), 1307 (s), 1514 (s), 1258 (m), 1188 (s), 1111 (s), 935 (s), 910 (m), 804 (m), 771 (vs), 743 (m), 714 (vs), 694 (s), 641 (m), 575 (s), 534 (m), 506 (s). PXRD of the bulk samples was in excellent agreement with the simulated PXRD pattern.
22. max = +25.97°) with I > 2σ(I) yielding R1 = 0.033. wR2 = 0.087, GOF = 1.047.
23. Janiak, C. J. Chem. Soc., Dalton Trans. 2000, 2885.
24. Spek, A. L. PLATON, A Multipurpose Cristallographic Tool; Utrecht University: Utrecht, The Netherlands, 2001.
25. 2 at a heating rate of 5 °C/min.