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27144545867
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40
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33645380034
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note
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2CH).
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41
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33645417459
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note
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2, 24.2 (CH(CH3)2)2.
-
-
-
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42
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-
33645400305
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-
note
-
There are reports in the patent literature claiming the synthesis of nongeminal β-haloethyltetramethylcyclopentadienes by the reaction of tetramethylcyclopentadienyllithium with 2-chloroethyl-p-toluenesulfonate or 1-bromo-2-chloroethane in THF or ether, respectively. The second method, giving a mixture of nongeminal and geminal isomers (variable ratio), has been recently used for the synthesis of 1,2,3,4-tetramethylbicyclo[2.4]hepta-1,3-diene. McConell, A. C.; Pogorzelec, P. J.; Slawin, A. M. Z.; Williams G. L.; Elliott, P. I. P.; Haynes, A.; Marr, A. C.; Cole-Hamilton, D. J. Dalton Trans. 2006, 91, and references therein.
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43
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33645405488
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note
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2).
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46
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(c) Filipponi, S.; Jones, J. N.; Johnson, J. A.; Cowley, A. H.; Grepioni, F.; Braga, D. Chem. Commun. 2003, 2716.
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47
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33645385041
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-
note
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2 = 15.2%.
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48
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17144425334
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51
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33645422836
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note
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2AgBr (%): C, 55.43, H, 5.42 N, 5.02. Found: C, 55.90, H, 5.34, N, 4.95.
-
-
-
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52
-
-
33645394044
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-
note
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2 = 10.81%.
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53
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0033440693
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33645422613
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note
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2 = 8.75%.
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56
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37049081149
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