Nucleophilic carbene complexes of manganocene

Organometallics

Volumn 20, Issue 17, 2001, Pages 3629-3631

  Abernethy, Colin D ^a   Cowley, Alan H ^a   Jones, Richard A ^a   Macdonald, Charles L B ^a   Shukla, Piyush ^a   Thompson, Laurence K ^b  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^b MEMORIAL UNIVERSITY OF NEWFOUNDLAND   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

MANGANOCENE; NUCLEOPHILIC CARBENE COMPLEXES;

CHEMICAL BONDS; CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

ORGANOMETALLICS;

EID: 0035921561     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0103916     Document Type: Article

References (13)

1. Abernethy, C. D.; Clyburne, J. A. C.; Cowley, A. H.; Jones, R. A. J. Am. Chem. Soc. 1999, 121, 2329.
2. Long, N. J. Metallocenes; Blackwell Science: Oxford, 1998; pp 54-55.
3. Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Am. Chem. Soc. 1984, 106, 2033.
4. Bottomley, F.; Keizer, P. N.; White, P. S. J. Am. Chem. Soc. 1988, 110, 137.
5. Heck, J.; Massa, W.; Weinig, P. Angew. Chem., Int. Ed. Engl. 1984, 23, 722.
6. + - carbene).
7. 1 = 0.0321. All structures were solved and refined using the Siemens SHELX PLUS 5.0 (PC) software package. In the case of 6, the presence of highly disordered THF molecule could not be modeled satisfactorily and was dealt with by use of the SQUEEZE routine in PLATON 98.
8. Sheldrick, G. M. SHELX PC Version 5.0; Siemens Analytical X-ray Instruments, Inc., 1994.
9. SQUEEZE program. Sluis, P. V. D.; Spek, A. L. Acta Crystallogr. 1990. A46, 194.
10. Magnetic measurements were made at Memorial University using a Quantum Design MPMS5S Squid magnetometer operating in the range 0.01-1.0 T.
11. Arduengo, A. J., III; Dias, H. V. R.; Harlow, R. L.; Kline, M. J. Am. Chem. Soc. 1992, 114, 5530.
12. Kuhn, N.; Kratz, T. Synthesis 1993, 561.
13. Abernethy, C. D.; Clyburne, J. A. C.; Cowley, A. H.; Jones, R. A.; Thompson, L. K.; Saillard, Y.-J. to be published.