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Kobayashi et al. have recently reported a similar strategy with their 'polymer incarceration' technique: Nishio, R.; Sugiura, M.; Kobayashi, S. Org. Lett. 2005, 7, 4831.
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note
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3): δ = 0.86-2.25 (bm, 24 H), 6.48-7.04 (bm, 35 H), 7.51-7.87 (bm, 14 H). The Pd content of 2 was determined to be 2.08% (theoretical value: 2.13%), which corresponds to a loading level of 0.20 mmol Pd/g, by X-ray fluorescence analysis.
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note
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13C NMR spectroscopy and MS analysis. The characterization data obtained agreed with previously reported data or that of commercial samples.
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note
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Water was added to these reactions since it seemed to make 2 easier to recover and handle. However, it had the effect of lengthening the reaction times. When recycling is not an issue, i-PrOH alone is the preferred solvent due to the solubility of the reactants in it, and thus shorter reaction times.
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