Catalytic asymmetric dihydroxylation using phenoxyethoxymethyl-polystyrene (PEM)-based novel microencapsulated osmium tetroxide (PEM-MC OsO4)

Organic Letters

Volumn 3, Issue 17, 2001, Pages 2649-2651

  Kobayashi, Shu ^a   Ishida, Tasuku ^a   Akiyama, Ryo ^a  

^a UNIVERSITY OF TOKYO   (Japan)

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ARTICLE;

EID: 0000600955     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0161965     Document Type: Article

References (39)

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36. 4 was recovered from the washings. This is a standard procedure for the preparation of microcapsules. Donbrow, M. Microcapsules and Nanoparticles in Medicine and Pharmacy; CRC Press: Boca Raton, FL, 1992. For details on microencapsulated catalysts, see refs 7 and 8.
37. Determined by weight and fluorescence X-ray analysis.
38. Confirmed by fluorescence X-ray analysis.
39. 4 was separated by filtration and reused (reuse data are shown in Table 2, entry 7). The crude product was purified by chromatography on silica gel to afford the desired cis-diol. The optical purity of the product was determined by HPLC analysis.